cas 6914-74-5, 1-CARBOXYCYCLOPROPANECARBOXAMIDE | Articles data ｜lookchem

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6914-74-5

Articles about 6914-74-5Total 3 be found

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Synthesis of 2,3-dihydro-1H-pyrrolo[1,2-a]benzimidazoles via the cyclopropyliminium rearrangement of substituted 2-cyclopropylbenzimidazoles
2-Cyclopropylbenzimidazole derivatives with various substituents in the small ring undergo cyclopropyliminium rearrangement into 2,3- dihydropyrrolobenzimidazoles substituted at positions 1, 2 or 3. The substrates containing a functional group in position 1 of the cyclopropane ring form products substituted at position 3. Substituents at position 2 in most cases lead to the formation of a mixture of isomers. The reaction can be directed to yield one of the isomers predominantly by varying the solvent polarity.
Salikov, Rinat F.,Platonov, Dmitry N.,Frumkin, Aleksandr E.,Lipilin, Dmitry L.,Tomilov, Yury V.
p. 3495 - 3505
(2013/04/23)

Process for the preparation of 1-aminocyclopropanecarboxylic acid hydrochloride
The present invention relates to a novel process for preparing 1-aminocyclopropanecarboxylic acid hydrochloride (ACC*HCl) of the formula STR1 ACC*HCl is prepared from a cyclopropane-1,1-dicarboxylic acid diester via an 1-aminocarbonylcyclopropanecarboxylic acid ester intermediate and an alkali metal salt or alkaline earth metal salt of 1-aminocarbonylcyclopropanecarboxylic acid. The process represents a simplification and gives improved product yields.
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(2008/06/13)

Stereochemical studies on the reactions catalyzed by the PLP-dependent enzyme 1-aminocyclopropane-1-carboxylate deaminase
The stereochemical course of 1-aminocyclopropane-1-carboxylate deaminase which catalyzes the fragmentation of the cyclopropane substrate to alpha -ketobutyrate and ammonia has been unraveled with the help of substrates stereospecifically labeled with deuterium and/or tritium, and this has afforded important information about the process occurring at the active site during enzymatic conversion.
Liu,Auchus,Walsh
p. 5335 - 5348
(2007/10/07)

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Chemical Properties

Melting Point: 185 °C (dec.)(lit.)
Boiling Point: 431.8°C at 760 mmHg
Flash Point:214.9°C
Density: 1.568g/cm³
Vapor Pressure: 1.16E-08mmHg at 25°C
Refractive Index: 1.4220 (estimate)
PKA: 3.55±0.20(Predicted)
PSA: 80.39000
LogP: 0.03680

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