Initiated tert-Butyl Hydroperoxide-loaded Low-temperature Autoxidation of Alkenes: Alternative Hydroperoxide Syntheses and the Preparation of a Complete Set of Reference Material
A complete set of characterization data for the allylic hydroperoxides prepared from 1-methylcyclohexene and the isomeric 4-methyloct-4-enes is presented.The data relies upon the preparation of allylic hydroperoxides by tert-butyl hydroperoxide-loaded autoxidations, singlet-ene oxidations and nucleophilic substitution reactions.Appropriate allylic alcohols and relevant scission products have been prepared to support the assignments given.
Courtneidge, John L.,Bush, Melanie,Loh, Lay-See
p. 1539 - 1548
(2007/10/02)
SYNTHESIS, THREE-DIMENSIONAL STRUCTURE, AND STEREOCHEMISTRY OF EPOXIDATION OF 1-CHLORO-2-METHYLENECYCLOHEXANE
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Vereshchagin, A. N.,Kovylyaeva, G. I.,Bakaleinik, G. A.
p. 91 - 95
(2007/10/02)
THE REACTION OF HYPOCHLOROUS ACID WITH OLEFINS. A CONVENIENT SYNTHESYS OF ALLYLIC CHLORIDES
The reaction of HOCl with more highly substituted olefins in methylene chloride affords allylic chlorides in 60-80percent isolated yields.The utility of the reaction is illustrated with the synthesis of Rose oxide and α-monoterpenes.
Hegde, Shridhar G.,Vogel, Martin K.,Saddler, John,Hrinyo, Tanya,Rockwell, Ned,et al.
p. 441 - 444
(2007/10/02)
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