723259-87-8

Basic information

• Product Name: 3-methylphenyl 2-iodobenzoate
• Synonyms: 3-methylphenyl 2-iodobenzoate
• CAS NO: 723259-87-8
• Molecular Formula: C14H11IO2
• Molecular Weight: 338.14041
• Mol File: 723259-87-8.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-methylphenyl 2-iodobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methylphenyl 2-iodobenzoate(723259-87-8)
• EPA Substance Registry System: 3-methylphenyl 2-iodobenzoate(723259-87-8)

Safety Data

• Hazardous Substances Data: 723259-87-8(Hazardous Substances Data)

Upstream product

• 609-67-6 2-Iodobenzoyl chloride 
• 108-39-4 3-methyl-phenol 
• 88-67-5 2-Iodobenzoic acid 

Relevant articles and documents

[N,P]-pyrrole PdCl2 complexes catalyzed the formation of dibenzo-α-pyrone and lactam analogues

We herein report the synthesis and catalytic application of a new family of [N,P] ligands based on the pyrrole ring with alpha-phosphine or phosphole units. Their palladium complexes (3a-d) were obtained in very good yields and their catalytic properties were evaluated in the direct intramolecular arylation to obtain both benzopyranones and phenanthridinones. The air stable complex 3a exhibited the best catalytic performance of this series of complexes, using 1 mol% of catalyst in combination with microwaves to promote this reaction.

Regioselectivity of the intramolecular biaryl coupling reaction of 3-substituted phenyl 2-iodobenzoate using a palladium reagent

This study investigated the regioselectivity of the intramolecular biaryl coupling reaction of the phenyl benzoate derivative which possesses a methyl or methoxy group at the meta-position of the phenoxy moiety. The type of base and the presence/absence of the phosphine ligand influenced the product ratio. A transition state model and the regioselectivity of the reaction are discussed.