727739-94-8Relevant articles and documents
One-pot multicomponent synthesis of azaindoles and pyrroles from one molecule of a silicon-tethered diyne and three or two molecules of organonitriles mediated by zirconocene
Zhang, Shaoguang,Sun, Xiaohua,Zhang, Wen-Xiong,Xi, Zhenfeng
experimental part, p. 12608 - 12617 (2010/06/14)
A zirconocene-mediated one-pot multicomponent synthesis process leading to the synthesis of pyrrolo[3,2-c]pyridine (5-azaindoles) and pyrrole derivatives has been developed starting from a silicon-tethered diyne and three or two different or identical org
Zirconocene-mediated intermolecular coupling of one molecule of Si-tethered Diyne with three molecules of organonitriles: One-pot formation of pyrrolo[3,2-c]pyridine derivatives via cleavage of C≡n triple bonds of organonitriles
Sun, Xiaohua,Wang, Congyang,Li, Zhiping,Zhang, Shiwei,Xi, Zhenfeng
, p. 7172 - 7173 (2007/10/03)
One Si-tethered diyne is coupled in one pot with three molecules of organonitriles promoted by a low-valent zirconocene species. Cleavage of one of the three C≡N triple bonds and cleavage of the two Si-C bonds take place to afford pyrrolo[3,2-c]pyridine derivatives after hydrolysis. Copyright