Synthesis and characterization of o-fluorosulfinylaniline. A comparative vibrational study of fluorinated sulfinylaniline series
The synthesis of o-fluorosulfinylaniline is reported with the aim to complete the fluorinated sulfinylaniline series. The FT-IR and Raman spectra of o-fluorosulfinylaniline are recorded and the fundamental modes of its vibrational frequencies are assigned
Páez Jerez, Ana L.,Alonso De Armi?o, Diego J.,Robles, Norma L.
p. 9894 - 9902
(2015/12/01)
N-heterocyclic carbene catalysis: Enantioselective formal [2+2] cycloaddition of ketenes and N-sulfinylanilines
Sultam of swing: Both enantiomers of 1,2-thiazetidin-3-one oxides were obtained in very good yields with excellent enantioselectivities when using N-heterocyclic carbene catalysts (see scheme; M.S.=molecular sieves, TBS=tert-butyldimethylsilyl). The products were easily converted into 3-oxo-β-sultams, α-mercapto amides, and β-mercapto amines through oxidation or reduction. Copyright
Jian, Teng-Yue,He, Lin,Tang, Cen,Ye, Song
supporting information; body text
p. 9104 - 9107
(2011/10/13)
INFLUENCE OF THE REPLACEMENT OF HYDROGEN ATOMS BY FLUORINE ON THE VIBRATIONAL ENERGY OF THE NSO GROUP AND 15N AND 17O NMR CHEMICAL SHIFTS IN N-SULFINYLARYLAMINES
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Zibarev, A. V.,Furin, G. G.,Korobeinicheva, I. K.,Fedotov, M. A.,Yakobson, G. G.
p. 2039 - 2044
(2007/10/02)
Umsetzungen von Metall- und Metalloidverbindungen mit mehrfunktionellen Molekuelen, XXVI Reaktionen von N-Sulfinylverbindungen mit Thioboranen
The reaction of N-sulfinylamines with (methylthio)organylboranes proceeds quantitatively according to R-N=S=O + 3 R'2BSCH3 -> RN(BR'2)-SSCH3 + CH3SSCH3 + 2O by insertion of the N=S double bond into the B-S sequence and a complex redox-reaction.Th
Meller, Anton,Maringgele, Walter,Fetzer, Hartmut
p. 1950 - 1961
(2007/10/02)
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