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74792-67-9

10,14-Retro-retinol is a naturally occurring chemical compound derived from retinol, which is a form of vitamin A. It is characterized by a unique structural feature where the carbon atoms at positions 10 and 14 are connected in a retro manner, creating a six-membered ring. 10,14-retro-retinol plays a significant role in various biological processes, including cell differentiation and embryonic development. It has been found to have potential applications in the treatment of certain skin conditions and as a component in anti-aging skincare products due to its ability to promote cell turnover and maintain skin health. Research on 10,14-retro-retinol is ongoing to further understand its mechanisms of action and explore its therapeutic potential.

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  • 74792-67-9 Structure

  • Basic information

    1. Product Name: 10,14-retro-retinol
    2. Synonyms: 10,14-retro-retinol
    3. CAS NO:74792-67-9
    4. Molecular Formula:
    5. Molecular Weight: 286.458
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 74792-67-9.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 10,14-retro-retinol(CAS DataBase Reference)
    10. NIST Chemistry Reference: 10,14-retro-retinol(74792-67-9)
    11. EPA Substance Registry System: 10,14-retro-retinol(74792-67-9)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 74792-67-9(Hazardous Substances Data)

74792-67-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 74792-67-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,4,7,9 and 2 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 74792-67:
(7*7)+(6*4)+(5*7)+(4*9)+(3*2)+(2*6)+(1*7)=169
169 % 10 = 9
So 74792-67-9 is a valid CAS Registry Number.

74792-67-9Relevant articles and documents

Thermal Sigmatropic Rearrangements of Vinylallenes Leading to 11-cis-Retinoids and the Novel Properties of 9-cis,11-cis,13-cis-Retinal and 11-cis,13-cis-Retinal

Knudsen, Christopher G.,Chandraratna, Roshantha A. S.,Walkeapaeae, Leslie P.,Chauhan, Yeshpal S.,Carey, Stephen C.,et al.

, p. 1626 - 1631 (2007/10/02)

The thermally induced sigmatropic hydrogen shift of vinylallene 5 provided a route to highly hindered 11-cis-retinoids.The coupling ot the hetero cuprate 14 with the propargyl benzoate 13b gave the vinylallene 5, which upon heating (69 deg C, 2 h) gave three geometrically isomeric retinoids: 11-sis (8), 11-cis,13-cis (9), and 9-cis,11-cis,13-cis (11).The fourth possible geometric isomer, 9-cis,11-cis (10), was unstable to the conditions of thermolysis and underwent further electrocyclizations to the tricyclic compound 22.The thermal rearramgement of 9,10-allene 5, though highly specific for the formation of 11-cis-retinoids, exhibits no selectivity in the formation of Δ9 and Δ13 double bonds.The highly hindered 11-cis,13-cis- and 9-cis,11-cis,13-cis-retinals, 9b and 11b, exhibit extraordinary electronic absorption spectra in that they exhibit their main maxima (302 nm) actually to the blue of the corresponding alcohols.The retinals 9b and 11b were thermally unstable and underwent clean isomerization to 13-cis-retinal and 9-cis,13-cis-retinal, respectively.

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