564-88-5

Basic information

• Product Name: 11-cis,13-cis-retinal
• Synonyms: 11-cis,13-cis-retinal
• CAS NO: 564-88-5
• Molecular Weight: 284.442
• Mol File: 564-88-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 11-cis,13-cis-retinal(CAS DataBase Reference)
• NIST Chemistry Reference: 11-cis,13-cis-retinal(564-88-5)
• EPA Substance Registry System: 11-cis,13-cis-retinal(564-88-5)

Safety Data

• Hazardous Substances Data: 564-88-5(Hazardous Substances Data)

Upstream product

• 17706-49-9 11,13-Di-cis-vitamin A 
• 22737-96-8 11-cis-retinol 
• 74916-02-2 12,14-retro-retinol 
• 116-31-4 all-trans-Retinal 
• 564-87-4 11-cis-retinal 
• 135322-87-1 Bis-(2,2,2-trifluoroethyl)-2-methyl-3-cyano-2-propenyl phosphonate 
• 56013-13-9 7-cis,9-cis-β-ionylideneacetaldehyde 
• 3899-20-5 (2E,4Z,6Z,8Z)-3,7-Dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester 
• 68-26-8 (2Z,4Z,6Z,8Z)-3,7-Dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraen-1-ol 
• 119718-30-8 7-cis,9-cis,11-cis-retinonitrile 
• 211235-94-8 (E)-5,5-diethoxy-3-methyl-1-(2,6,6-trimethylcyclohex-1-enyl)pent-2-en-1-ol 
• 1209-68-3 3-methyl-5-(2,6,6-trimethylcyclohex-1-enyl)penta-2, 4-dienal 
• 162889-29-4 C₉H₁₇LiO₂ 
• 134962-99-5 4-Methyl-6-[(1E,3E)-2-methyl-4-(2,6,6-trimethyl-cyclohex-1-enyl)-buta-1,3-dienyl]-5,6-dihydro-2H-pyran-2-ol 

Downstream Products

• 514-85-2 9-cis vitamin A aldehyde 
• 472-86-6 13-cis-vitamin A aldehyde 
• 116-31-4 all-trans-Retinal 
• 56085-55-3 7-cis,9-cis,13-cis-retinal 
• 56085-53-1 7,9,13-tricis-retinal 
• 67737-37-5 All-cis-Retinal 
• 33532-44-4 4-keto-all-trans-retinal 
• 71423-68-2 4-hydroxy-13-cis-retinal 
• 18344-42-8 4-hydroxy-all-trans-retinal 
• 739-13-9 5,6-epoxy-5,6-dihydroretinal 
• 71423-69-3 4-keto-13-cis-retinal 
• 52647-48-0 Butyl-[(2Z,4Z,6E,8E)-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraen-(E)-ylidene]-amine 

Relevant articles and documents

Selective isomerization of retinal upon two-photon excitation

The products of photo-isomerization when excited directly up to the two-photon-allowed 1Ag- excited state of alltrans and five cis isomers of retinal were determined. The composition of the isomers at the photo-stationary state was drastically changed as compared to one-photon excitation. The production of the 13-cis isomer was selectively increased, and the production of the dicis isomers was observed in the case of a direct excitation upon the 31Ag- state, although they were hard to be produced by one-photon excitation in n-hexane solution. These results clearly evidenced that there exist isomerization pathways via two-photon-allowed excited states.

Photoisomerization of polyenes. 30. Quantum chain processes in photoisomerization of the all-trans, 7-cis, and 11-cis isomers of retinal

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A new prenylation method using the lithium enolate of prenal. Reaction with polyunsaturated aldehydes. A short access to retinal

The enolate of prenal 1 prepared from the corresponding silyl enol ether 2 or enol acetate 3 led to a γ-regiospecific reaction with polyunsaturated aldehydes 4 yielding dihydropyrans 5 leading after hydrolysis to polyenals 7. This process allows the introduction of the isoprenyl skeleton. A synthesis of retinal, from β-ionylidenacetaldehyde is reported.