- Photoinduced cleavage of N-N bonds of aromatic hydrazines and hydrazides by visible light
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A photocatalytic system involving [Ru(bpyrz)(PFH, visible light, and air has been developed for cleavage of the N-N bonds of hydrazines and hydrazides. This catalytic system is generally effective for N,N-disubstituted hydrazine and hydrazide derivatives, including arylhydrazides, N-alkyl-N-arylhydrazines, and N,N-diarylhydrazines. The utility of this cleavage reaction has been demonstrated by synthesizing a variety of secondary aromatic amines. Georg Thieme Verlag Stuttgart ? New York.
- Zhu, Mingzhao,Zheng, Nan
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supporting information; experimental part
p. 2223 - 2236
(2011/09/15)
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