Synthesis of N-substituted-2-Aminobenzothiazoles by ligand-Free copper(I)-Catalyzed cross-Coupling reaction of 2-haloanilines with isothiocyanates www.eurjoc.org
A novel and efficient formation of N-substituted-2-aminobenzothiazoles by a ligand-free copper(I)-catalyzed one-pot cascade process was developed. A variety of isothiocyanates coupled with 2-iodoanilines to give N-substituted-2-amino-benzothiazoles in mod
Shen, Guodong,Lv, Xin,Bao, Weiliang
scheme or table
p. 5897 - 5901
(2010/03/01)
MASS SPECTRA OF 2-PHENYLAMINOBENZOTHIAZOLE DERIVATIVES AND THEIR ISOMERS
The mass spectra of isomeric 2-arylaminobenzothiazoles and 2-imino-3-aryl- and 2-aryliminobenzothiazolines were investigated.Characteristic of the elimination of the ortho substituent of the aromatic ring, which leads to the formation of cyclic fragments