786709-32-8

Basic information

• Product Name: Benzenesulfonamide, N-[(1R)-2-hydroxy-1-methylethyl]-4-methyl- (9CI)
• Synonyms: Benzenesulfonamide, N-[(1R)-2-hydroxy-1-methylethyl]-4-methyl- (9CI);N-Tosyl-D-Alaninol
• CAS NO: 786709-32-8
• Molecular Formula: C₁₀H₁₅NO₃S
• Molecular Weight: 229.296
• Product Categories: METHYL
• Mol File: 786709-32-8.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzenesulfonamide, N-[(1R)-2-hydroxy-1-methylethyl]-4-methyl- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-[(1R)-2-hydroxy-1-methylethyl]-4-methyl- (9CI)(786709-32-8)
• EPA Substance Registry System: Benzenesulfonamide, N-[(1R)-2-hydroxy-1-methylethyl]-4-methyl- (9CI)(786709-32-8)

Safety Data

• Hazardous Substances Data: 786709-32-8(Hazardous Substances Data)

Upstream product

• 786709-29-3 (1S,3R,6S)-3,6-dihydro-3,6-dimethyl-2-tosyl-1λ⁴,2-thiazine 1-oxide 
• 4104-47-6 N-sulfinyl-p-toluenesulfonamide 
• 35320-23-1 (R)-2-aminopropan-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 177971-32-3 (2R)-2-methyl-1-(p-tolylsulfonyl)aziridine 
• 214190-58-6 4-Methyl-N-((R)-1-methyl-dec-9-enyl)-benzenesulfonamide 

Relevant articles and documents

Asymmetric hetero-Diels-Alder reactions of N-sulfinyl dienophiles using chiral bis(oxazoline)-copper(II) and -zinc(II) triflates

Asymmetric hetero-Diels-Alder (HDA) reactions of N-sulfinyl dienophiles using bis(oxazoline)-copper(II) and -zinc(II) triflates are described. The cycloadditions with cyclic and acyclic 1,3-dienes have been studied. In most cases, good enantioselectivitie

Absolute configuration of the polyazamacrolides, macrocyclic polyamines produced by a ladybird beetle

The absolute configuration of the polyazamacrolides, oligomeric macrocycles from the pupal defensive secretion of Epilachna borealis, was determined by comparison of derivatives of the natural material with enantiomerically pure synthetic samples. Samples of a mixture of three (ω- 1)-(2-hydroxy-ethylamino)alkanoic acids and of the corresponding aza-lactones were synthesized from (R)-alaninol. Gas chromatographic comparison of MTPA- amides of the synthetic aza-lactones with the MTPA-amides of aza-lactones prepared from the natural material established that the polyazamacrolides have the (R)-configuration at all stereogenic centers.