799-34-8Relevant articles and documents
Promising prospects for using partially fluorinated alcohols as O-nucleophilic reagents in organofluoric synthesis
Il'in,Il'in,Bakhmutov,Furin,Pokrovskii
, p. 405 - 418 (2008/02/02)
Perfluoroolefins react with isopropyl alcohol under the conditions of radical initiation to form partially fluorinated aliphatic alcohols. The reactions of these alcohols with hexafluoropropylene and compounds containing labile halogen atoms (in particular, with allyl bromide and epichlorohydrin) were studied.
An approach to fluorinated surface coatings via photoinitiated cationic cross-linking of mixed epoxy and fluoroepoxy systems
Matuszczak, Stephen,Feast, W. James
, p. 269 - 277 (2007/10/03)
The synthesis and characterisation of four polyfluorinated monoepoxides is described. These fluoroepoxy monomers were cationically polymerised either neat or as mixtures with diglycidylether of bisphenol-A using the initiator system (CH3CH2)3Al/H2O (2/1) or the photoinitiator Ph2I+, PF6-. Contact angle measurements indicated that, in favourable cases, the fluorinated epoxide monomer surface segregated at low loadings to give significant lowering of the surface free energy of photocured films of diglycidylether of bisphenol-A.
FLUORINE-CONTAINING 2,3-EPOXYPROPYL ETHERS. SYNTHESIS AND SPECTRAL CHARACTERISTICS
Solov'ev, D. V.,Kolomenskaya, L. V.,Rodin, A. A.,Zenkevich, I. G.,Lavrent'ev, A. N.
, p. 611 - 615 (2007/10/02)
Polyfluoroalkyl 2,3-epoxypropyl ethers were prepared by the reactions of fluoro olefins with 2,3-epoxy-1-propanol in presence of potassium fluoride and under the conditions of phase-transfer catalysis. 1H and 19F NMR- and mass-spectral characteristics of the polyfluoroalkyl ethers were determined.