81678-18-4

Basic information

• Product Name: furanogermenone
• Synonyms: furanogermenone
• CAS NO: 81678-18-4
• Molecular Formula: C15H20O2
• Molecular Weight: 232.321
• Mol File: 81678-18-4.mol

Chemical Properties

• Boiling Point: 346.6°C at 760 mmHg
• Flash Point: 162.5°C
• Appearance: /
• Density: 0.992g/cm³
• Vapor Pressure: 5.69E-05mmHg at 25°C
• Refractive Index: 1.49
• CAS DataBase Reference: furanogermenone(CAS DataBase Reference)
• NIST Chemistry Reference: furanogermenone(81678-18-4)
• EPA Substance Registry System: furanogermenone(81678-18-4)

Safety Data

• Hazardous Substances Data: 81678-18-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H20O2/c1-10-5-4-6-11(2)14(16)8-13-12(3)9-17-15(13)7-10/h5,9,11H,4,6-8H2,1-3H3/b10-5-/t11-/m0/s1

Upstream product

• 1416546-00-3 (5R,6S)-3,6-dimethyl-6-vinyl-4,5,6,7-tetrahydrobenzofuran-5-yl pivalate 
• 1416545-98-6 (1R,2S,5S)-2-methyl-4-oxo-5-(2-methyloxiran-2-yl)-4-oxo-2-vinylcyclohexyl pivalate 
• 1416545-96-4 (1R,2S,5S)-2-methyl-4-oxo-5-(prop-1-en-2-yl)-2-vinylcyclohexyl pivalate 
• 1416545-94-2 C₁₅H₂₂O₃ 
• 1416545-92-0 (1R,5R)-2-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-3-enyl pivalate 
• 1416546-06-9 (5R,6S)-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofuran-5-ol 
• 1416546-04-7 (S)-3,6-dimethyl-6-vinyl-6,7-dihydrobenzofuran-5(4H)-one 
• 1416546-02-5 (5R,6S)-3,6-dimethyl-6-vinyl-4,5,6,7-tetrahydrobenzofuran-5-ol 
• 81678-31-1 (E)-(S)-3,6,10-Trimethyl-4,5,6,7,8,11-hexahydro-cyclodeca[b]furan-5-ol 

Downstream Products

• 81678-40-2 (2S)-5-(benzyloxy)-2-methylpentan-1-ol 
• 81678-38-8 Benzoic acid (S)-5-methanesulfonyloxy-6-[2-(2-methanesulfonyloxy-propyl)-4-methyl-furan-3-yl]-4-methyl-hexyl ester 
• 81678-37-7 Benzoic acid (S)-5-hydroxy-6-[2-(2-hydroxy-propyl)-4-methyl-furan-3-yl]-4-methyl-hexyl ester 
• 81678-39-9 3-((E)-(S)-6-Benzyloxy-3-methyl-hex-1-enyl)-4-methyl-2-((Z)-propenyl)-furan 

Relevant articles and documents

Non-natural elemane as the stepping stone for the synthesis of germacrane and guaiane sesquiterpenes

The synthesis of hydroxyelemane 5 from (R)-carvone and its utilization as a common synthetic scaffold to produce structurally diverse germacrane and guaiane sesquiterpenes are described. A highly enantio- and stereoselective biomimetic tandem oxy-Cope/ene rearrangement was used as the key reaction to access the 10-membered macrocyclic core of germacranes and the condensed 5-7 carbocycles of guaiane sesquiterpenes. Additionally, reactions of furanoguaianes under acidic or oxidizing reagents have been investigated, and preliminary results of these conversions are presented.

ABSOLUTE STEREOSTRUCTURE OF FURANOGERMENONE, A BIOLOGICALLY ACTIVE SESQUITERPENE FROM ZEDOARIAE RHIZOMA

The absolute stereostructure of a new bioactive sesquiterpene named furanogermenone (1), which was isolated from Chinese Zedoariae Rhizoma, has been determined on the basis of chemical and physicochemical evidence.