Palladium-catalyzed cross-couplings of allylic phosphates
A range of palladium-catalyzed cross-coupling reactions can be performed using allylic phosphates as electrophiles. Both conventional heating and microwave irradiation can be used.
Maslak, Veselin,Tokic-Vujosevic, Zorana,Saicic, Radomir N.
supporting information; experimental part
p. 1858 - 1860
(2009/07/19)
Prenylation of aromatics. Lithium-ammonia reduction of o-silylated tertiary cinnamyl alcohols
Silyl protected phenolic or non-phenolic tertiary cinnamyl alcohols undergo metalammonia induced hydrogenolysis with concomitant double bond isomerization, thus providing a unique entrance to prenyl substituted aromatics. Chiral alcohols yielded E:Z mixtu
Ballester, Pablo,Capo, Magdalena,Saa, Jose M.
p. 1339 - 1342
(2007/10/02)
AN EFFICIENT REGIO- AND STEREOSPECIFIC ALKENYLATION OF PHENOLIC ETHERS BY PRENYL AND GERANYL DIISOPROPYL PHOSPHATES
Prenyl and geranyl diisopropyl phosphates readily alkenylate a variety of phenolic ethers regio- and stereospecifically without any appreciable side reactions.
Araki, Shuki,Manabe, Shin-ichi,Butsugan, Yasuo
p. 797 - 800
(2007/10/02)
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