83036-40-2Relevant academic research and scientific papers
Palladium-catalyzed cross-couplings of allylic phosphates
Maslak, Veselin,Tokic-Vujosevic, Zorana,Saicic, Radomir N.
supporting information; experimental part, p. 1858 - 1860 (2009/07/19)
A range of palladium-catalyzed cross-coupling reactions can be performed using allylic phosphates as electrophiles. Both conventional heating and microwave irradiation can be used.
Prenylation of aromatics. Lithium-ammonia reduction of o-silylated tertiary cinnamyl alcohols
Ballester, Pablo,Capo, Magdalena,Saa, Jose M.
, p. 1339 - 1342 (2007/10/02)
Silyl protected phenolic or non-phenolic tertiary cinnamyl alcohols undergo metalammonia induced hydrogenolysis with concomitant double bond isomerization, thus providing a unique entrance to prenyl substituted aromatics. Chiral alcohols yielded E:Z mixtu
AN EFFICIENT REGIO- AND STEREOSPECIFIC ALKENYLATION OF PHENOLIC ETHERS BY PRENYL AND GERANYL DIISOPROPYL PHOSPHATES
Araki, Shuki,Manabe, Shin-ichi,Butsugan, Yasuo
, p. 797 - 800 (2007/10/02)
Prenyl and geranyl diisopropyl phosphates readily alkenylate a variety of phenolic ethers regio- and stereospecifically without any appreciable side reactions.
