Antiproliferative effect and apoptotic activity of linear geranylphenol derivatives from phloroglucinol and orcinol
Sixteen synthetic linear derivatives geranylphenols, were obtained from phloroglucinol and orcinol, and cytotoxic activity was evaluated in vitro against cancer cell lines (HT-29, PC-3, MDA-MB231, DU-145) and one non-tumor cell line, human dermal fibrobla
Taborga, Lautaro,Espinoza, Luis,Moller, Alejandra,Carrasco, Héctor,Cuellar, Mauricio,Villena, Joan
Synthesis and nmr structure determination of new linear geranylphenols by direct geranylation of activated phenols
The known geranylhydroquinone 2, geranylorcinol 4 and the derivative (E)-4-(3,7-dimethylocta-2,6-dienyl)-5-methylbenzene-1,3-diol 5, were prepared by Electrophilic Aromatic Substitution (EAS) reactions between the corresponding phenol derivatives containi
Taborga, Lautaro,Vergara, Alejandra,Fernandez, Maria Jose,Osorio, Mauricio,Carvajal, Marcela,Madrid, Alejandro,Marilaf, Francisco,Carrasco, Hector,Catalan, Luis Espinoza
p. 1790 - 1796
(2013/09/24)
IRON-MEDIATED AROMATIC ALLYLATION
Electron rich aromatic and heteroaromatic compounds react with (η3-allyl)Fe(CO)4BF4 to produce allylated aromatics in moderate to good yields.Unsymmetrically substituted allyl complexes afford the corresponding butenyl-, 1,1-dimethylallyl-, cinnamyl-, and geranyl-derivatives with moderate to excellent regioselectivity and complete stereoselectivity.
Dieter, Janice W.,Li, Zhong,Nicholas, Kenneth M.
p. 5415 - 5418
(2007/10/02)
AN EFFICIENT REGIO- AND STEREOSPECIFIC ALKENYLATION OF PHENOLIC ETHERS BY PRENYL AND GERANYL DIISOPROPYL PHOSPHATES
Prenyl and geranyl diisopropyl phosphates readily alkenylate a variety of phenolic ethers regio- and stereospecifically without any appreciable side reactions.
Araki, Shuki,Manabe, Shin-ichi,Butsugan, Yasuo
p. 797 - 800
(2007/10/02)
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