83110-46-7

Basic information

• Product Name: 3,7-dimethyl-1-(p-tolylsulfonyl)-2,6-octadiene
• Synonyms: 3,7-dimethyl-1-(p-tolylsulfonyl)-2,6-octadiene
• CAS NO: 83110-46-7
• Molecular Weight: 292.442
• Mol File: 83110-46-7.mol

Chemical Properties

• CAS DataBase Reference: 3,7-dimethyl-1-(p-tolylsulfonyl)-2,6-octadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 3,7-dimethyl-1-(p-tolylsulfonyl)-2,6-octadiene(83110-46-7)
• EPA Substance Registry System: 3,7-dimethyl-1-(p-tolylsulfonyl)-2,6-octadiene(83110-46-7)

Safety Data

• Hazardous Substances Data: 83110-46-7(Hazardous Substances Data)

Upstream product

• 106-24-1 Geraniol 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 115-95-7 linalool acetate 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 141-12-8 neryl acetate 
• 119784-71-3 5-<(E)-3,7-dimethyl-2,6-octadienylthio>-1-phenyl-1H-tetrazole 
• 72863-23-1 3,7-dimethyl-3-(p-tolylsulfonyl)-1,6-octadiene 

Downstream Products

• 105479-70-7 C₃₄H₄₆O₄S₂ 
• 105479-70-7 C₃₄H₄₆O₄S₂ 
• 105479-71-8 C₃₄H₄₆O₄S₂ 

Relevant articles and documents

SINGLE-STEP PREPARATION OF ALLYLIC SULFIDES HAVING 1-PHENYLTETRAZOLE-5-THIO GROUP FROM ALLYLIC ALCOHOLS USING S,S'-BIS(1-PHENYL-1H-TETRAZOL-5-YL) DITHIOCARBONATE AND REACTIONS INVOLVING THE ALLYLIC SULFIDES

The reaction of allylic alcohols and S,S'-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate (1) gave allylic sulfides having 1-phenyltetrazole-5-thio group in a single step.Furthermore, these allylic sulfides could be applied to carbon-carbon bond and carbon-sulfur bond formations by using Grignard reagents or carbanions in the presence of catalytic amount of copper(I) bromide or palladium (0), respectively.

REGIO- AND STEREOCONTROLLED SYNTHESIS OF ALLYLIC p-TOLYL SULFONES CATALYZED BY PALLADIUM (0) COMPLEX

The reaction of allyl esters with sodium p-tolylsulfinate in tetrahydrofuran and methanol catalyzed by Pd(PPh3)4 gave the regio- and stereocontrolled allylic p-tolyl sulfones in good yields at room or lower temperature.