K2CO3-promoted formation of aryl esters from primary aryl amides by the acyl-acyl exchange process
A new acyl-acyl exchange reaction has been developed for the formation of aryl esters from primary aryl amides. The reaction could occur under mild reaction conditions with catalytic quantities of K2CO3, and could afford moderate to good yields of the desired products.
Bian, Yongjun,Qu, Xingyu
supporting information
p. 3869 - 3872
(2016/05/24)
Isolation of an inclusion complex of naphthol and its benzoate as an intermediate in the solvent-free benzoylation reaction of naphthol
A study was performed on isolation of an inclusion complex of naphthol and its benzoate as an intermediate in the solvent-free benzoylation reaction of naphthol. Solvent-free benzoylation reactions were carried out by heating a stirred mixture of phenols or naphthols and benzoyl chloride. The structure of the 2 : 1 inclusion complex of 2,3 naphthalenediol and its p-methylbenzoate was studied by X-ray analysis.