Total synthesis of (-)-colombiasin A and (-)-elisapterosin B
Intramolecular cycloaddition reactions are central in the total syntheses of colombiasin A (1) and elisapterosin B (2) described, which use (-)-dihydrocarvone as the starting material. A Moore rearrangement of a vinylcyclobutene is used to initiate the cycloaddition.
Harrowven, David C.,Pascoe, David D.,Demurtas, Daniela,Bourne, Heather O.
p. 1221 - 1222
(2007/10/03)
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