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857678-55-8

(S)-Tol-Binap RuCl2 AMPY is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • Dichloro[(S)-(-)-2,2’-bis(di-p-tolylphosphino)-1,1’-binaphthyl](2-aminomethylpyridine)ruthenium(II) RuCl2(AMPY)[(S)-Tol-Binap]

    Cas No: 857678-55-8

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  • Strem Chemicals, Inc.
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  • 857678-55-8 Structure

  • Basic information

    1. Product Name: (S)-Tol-Binap RuCl2 AMPY
    2. Synonyms: (S)-Tol-Binap RuCl2 AMPY;Dichloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](2-aMinoMethylpyridine)rutheniuM(II) RuCl2(AMPY)[(S)-Tol-Binap]
    3. CAS NO:857678-55-8
    4. Molecular Formula: C54H48Cl2N2P2Ru
    5. Molecular Weight: 959.92
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 857678-55-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: yellow/Powder
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. Sensitive: air sensitive
    10. CAS DataBase Reference: (S)-Tol-Binap RuCl2 AMPY(CAS DataBase Reference)
    11. NIST Chemistry Reference: (S)-Tol-Binap RuCl2 AMPY(857678-55-8)
    12. EPA Substance Registry System: (S)-Tol-Binap RuCl2 AMPY(857678-55-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 857678-55-8(Hazardous Substances Data)

857678-55-8 Usage

Reactions

Efficient catalyst used in the asymmetric hydrogenation of tert-alkyl ketones.

Check Digit Verification of cas no

The CAS Registry Mumber 857678-55-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,5,7,6,7 and 8 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 857678-55:
(8*8)+(7*5)+(6*7)+(5*6)+(4*7)+(3*8)+(2*5)+(1*5)=238
238 % 10 = 8
So 857678-55-8 is a valid CAS Registry Number.

857678-55-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name [dichloro((S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl)(α-picolylamino)ruthenium(II)]

1.2 Other means of identification

Product number -
Other names RuCl2[(S)-tolbinap)](pica)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:857678-55-8 SDS

857678-55-8Upstream product

857678-55-8Relevant articles and documents

RUTHENIUM COMPLEX AND PROCESS FOR PRODUCING TERT-ALKYL ALCOHOL THEREWITH

-

Page/Page column 4, (2010/11/28)

A tert-alkyl ketone, pinacolone was hydrogenated under pressurized hydrogen in the presence of a ruthenium complex (S)-1 and a base, and corresponding (S)-3,3,-dimethyl-2-butanol was thereby obtained in 100% yield and 97% ee.

Asymmetric hydrogenation of tert-alkyl ketones

Ohkuma, Takeshi,Sandoval, Christian A.,Srinivasan, Rajagopal,Lin, Quinghong,Wei, Yinmao,Muniz, Kilian,Noyori, Ryoji

, p. 8288 - 8289 (2007/10/03)

A combined system of RuCl2(tolbinap)(pica) and an alkaline or organic phosphazene base catalyzes asymmetric hydrogenation of sterically congested tert-alkyl ketones (TolBINAP = 2,2-bis(di-4-tolylphosphino)-1,1-binaphthyl, PICA = α-picolylamine). Hydrogenation with RuH(η1-BH4)(tolbinap)(pica) does not require any strong base. Alcoholic solvents strongly affect the catalytic efficiency. The reaction proceeds smoothly in ethanol under 1-20 atm of H2 and at room temperature with a substrate to catalyst molar ratio of up to 100000. Various aliphatic, aromatic, heteroaromatic, and olefinic tert-alkyl ketones are convertible to the corresponding chiral carbinols in high enantiomeric purity. Olefinic and heteroaromatic functions are left intact. Certain cyclic ketones are also usable. The mode of enantioface selection is consistent and predictable. Copyright

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