861437-15-2Relevant articles and documents
C-H?F, C-H?O interactions in the crystal structure of 2-(2-nitrophenyl)-3-pentafluorophenyl-oxirane and 2-pentafluorophenyl-3-phenyl- 1-(p-tosyl)-aziridine
Zhang, Xiu-Lian,Yin, Wei,Zhu, Shi-Fa,Cao, Man Li,Zhu, Shi-Zheng
, p. 252 - 256 (2012)
Existence and nature of C-H?F, C-H?O interactions in 2-(2-nitrophenyl)-3-pentafluorophenyl-oxirane (1) and 2-pentafluorophenyl-3- phenyl-1-(p-tosyl)-aziridine (2) are discussed. In compound 1 with a linear molecule, C-H?F, C-H?O hydrogen bonds assemble ad
The first example of catalytic aziridination mediated by arsonium ylides: Preparation of trans-pentafluorophenyl-containing aziridines
Zhu, Shifa,Liao, Yuanxi,Zhu, Shizheng
, p. 1429 - 1432 (2007/10/03)
Triphenylarsine catalyzes the formation of aziridines from tosyl imines and aromatic diazo compounds in a one-pot reaction. It is the first example of catalytic aziridination mediated by arsonium ylides. It gave aziridines in excellent diastereoselectivity with pentafluorophenyl diazomethane as the substrate. This catalytic reaction is complementary with the reaction mediated by sulfur ylides. Georg Thieme Verlag Stuttgart.