- In situ protection and deprotection of amines for iron catalyzed oxidative amidation of aldehydes
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An environmentally friendly synthetic route by the application of CO2 to synthesize amides via in situ protection and deprotection of amines for iron catalyzed oxidative amidation of aldehydes was developed. Various secondary and tertiary amides have been synthesized in moderate to good yields under mild and neutral reaction conditions. The use of amine hydrochloride salts and hence base for neutralization step is totally avoided in this protocol.
- Bathini, Thulasiram,Rawat, Vikas S.,Bojja, Sreedhar
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supporting information
p. 5656 - 5660
(2015/09/15)
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- PLANT DISEASE CONTROL AGENT, AND PLANT DISEASE CONTROL METHOD
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Disclosed is a plant disease control agent comprising an amide compound represented by the formula (1) as an active ingredient. (1): wherein X1 represents a fluorine atom or a methoxy group; X2 represents a hydrogen atom, a halogen atom, a C1-C4 alkyl group, a C2-C4 alkenyl group, a C1-C4 haloalkyl group, a C1-C4 alkoxy group, a C1-C4 alkylthio group, a C1-C4 hydroxyalkyl group and so on; Z1 represents an oxygen atom or a sulfur atom; A1 represents a single bond, -CH2- and so on; and G1 represents a group CR6R7R8, a C3-6 cycloalkyl group and so on.
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Page/Page column 37-38
(2010/05/13)
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- Amides and formamidines with antinociceptive activity (note II)
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Forty amides, formamidines and trifluoromethylsulfonylamides bearing on the nitrogen a cyclohexyl residue, eventually 2-substituted, were prepared and tested for analgesic activity against a chemical stimulus. Good activity was exhibited by amides 9, 11 and 28, by formamidine 34, as well as by triflylamide 40. Eleven additional compounds exhibited a moderate activity.
- Pau,Boatto,Cerri,Palomba,Nicolai,Sparatore,Varoni
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p. 1291 - 1299
(2007/10/02)
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