86623-72-5Relevant academic research and scientific papers
Synthesis and characterization of silicon-based group 14 dendrimers Si{(CH2)2Sn[(CH2)4MPh 3]3}4 (M = Ge, Sn)
Schumann, Herbert,Aksu, Yilmaz
, p. 397 - 402 (2008/10/09)
The catalytic hydrogermylation of Si(CH=CH2)4 with Ph3GeH yielded Si(CH2CH2GePh3) 4 (1). In contrast, Sn(CH=CH2)4 and Sn(CH 2CH=CH2)s
Synthesis and characterization of some organo-all-tin dendrimers with different peripheral substituents
Schumann, Herbert,Aksu, Yilmaz,Wassermann, Birgit C.
, p. 1703 - 1712 (2007/10/03)
The synthesis of the first all-tin-dendrimer Sn[(CH2) 4SnPh3]4 (2) results from complete hydrostannation of tetra(but-3-enyl)stannane (1) with triphenyltin hydride. Selective cleavage of one phenyl group from ea
Synthesis, NMR studies and molecular structures of 2 and 2(S)(CH2)3
Dakternieks, Dainis,Jurkschat, Klaus,Schollmeyer, Dieter,Wu, Hong
, p. 145 - 150 (2007/10/02)
Reaction of bis(dichlorophenylstannyl)propane (PhCl2Sn)2(CH2)3 with Na2S gives the dimeric compound 2 (1) which has been shown by X-ray crystallography to contain six-membered SnC3SnS rings as well as eight-membered Sn4S4 rings.NMR studies
Transfer off hydrogen from carbon-hydrogen bonds. Synthesis, structure, and reactions of tris[(triphenylstannyl)methyl]methane
Ducharme, Yves,Latour, Stephan,Wuest, James D.
, p. 208 - 211 (2008/10/08)
Compounds in which a carbon-hydrogen bond is adjacent to several carbon-metal bonds promise to be particularly good donors of hydrogen. The synthesis, structure, and redox reactions of one member of this group of compounds, tris[(triphenylstannyl)methyl]methane (2), are reported. Triphenylcarbenium is reduced to triphenylmethane less rapidly by stannane 2 than by bis[(triphenylstannyl)methyl]methane (11). The unexpectedly low reactivity of stannane 2 is due to the adoption of a C3 conformation in which the central carbon-hydrogen bond is sterically shielded and gauche to the adjacent carbon-tin bonds.
