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1124-19-2

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1124-19-2 Usage

Chemical Properties

Clear colorless liquid,darkening on light exposure

Uses

Phenyltin trichloride is used to produce 3-phenyl-cyclohexanone with cyclohex-2-enone. And it is also used in pharmaceutical intermediates.

Check Digit Verification of cas no

The CAS Registry Mumber 1124-19-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,2 and 4 respectively; the second part has 2 digits, 1 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1124-19:
(6*1)+(5*1)+(4*2)+(3*4)+(2*1)+(1*9)=42
42 % 10 = 2
So 1124-19-2 is a valid CAS Registry Number.
InChI:InChI=1/C6H5.3ClH.Sn/c1-2-4-6-5-3-1;;;;/h1-5H;3*1H;/q;;;;+3/p-3/rC6H5Cl3Sn/c7-10(8,9)6-4-2-1-3-5-6/h1-5H

1124-19-2 Well-known Company Product Price

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  • (Code)Product description
  • CAS number
  • Packaging
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  • Detail
  • Alfa Aesar

  • (71157)  Phenyltin trichloride   

  • 1124-19-2

  • 5g

  • 565.0CNY

  • Detail
  • Alfa Aesar

  • (71157)  Phenyltin trichloride   

  • 1124-19-2

  • 25g

  • 2671.0CNY

  • Detail
  • Aldrich

  • (277231)  Phenyltintrichloride  98%

  • 1124-19-2

  • 277231-5G

  • 375.57CNY

  • Detail
  • Aldrich

  • (277231)  Phenyltintrichloride  98%

  • 1124-19-2

  • 277231-25G

  • 1,918.80CNY

  • Detail

1124-19-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Phenyltin Trichloride

1.2 Other means of identification

Product number -
Other names trichloro(phenyl)stannane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1124-19-2 SDS

1124-19-2Relevant articles and documents

Ballczo, H.,Schiffner, H.

, p. 3 - 18 (1956)

Tri- and diorganostannates containing 2-(N,N-dimethylaminomethyl)phenyl ligand

?vec, Petr,?erno?ková, Eva,Padělková, Zdeňka,R??i?ka, Ale,Hole?ek, Jaroslav

, p. 2475 - 2485 (2010/11/16)

The C,N-chelated tri and diorganotin(IV) chlorides react with both protic mineral acids and carboxylic acids. The nitrogen atom of the LCN ligand (where LCN is 2-(dimethylaminomethyl)phenyl) is thus quarternized - protonated and new Sn-X bond (X = Cl, Br, I or the remainder of the starting acid used) is simultaneously formed. The set of zwitterionic tri and diorganostannates containing protonated 2-(dimethylaminomethyl)phenyl-moiety was prepared and structurally characterized by multinuclear NMR spectroscopy and XRD techniques. In all these cases, the intramolecular N-H?X bond is present in the molecule. Despite the central tin atom remains five-coordinated (except for the [HLCNH]+[(n-Bu)2SnCl(NO 3)2]-) and reveals a distorted trigonal bipyramidal geometry, the 119Sn NMR chemical shift values of these zwitterionic stannates are somewhat shifted to the higher field than corresponding starting C,N-chelated tri and diorganotin(IV) halides. Reactions of C,N-chelated organotin(IV) halides with various Lewis acids are also discussed.

Synthesis and reactivity of stannyloligosilanes, I. Stannyloligosilane chains containing SiMe2 moieties

Uhlig, Frank,Kayser, Christian,Klassen, Ralph,Hermann, Uwe,Brecker, Lothar,Schürmann, Markus,Ruhland-Senge, Karin,Englich, Ulrich

, p. 278 - 287 (2007/10/03)

Stannyloligosilanes 1 and 2 with terminal organotin groups are available by reacting alkali metal tri-or diorganostannides with α,ω-dichloro-or difluorosilanes, or by treatment of organochlorostannanes with α,ω-difluorosilanes in the presence of magnesium. Attempts to functionalize the triorganotin derivatives 2 by halogenation reagents did not result in the halogen compounds 5; instead cleavage of silicon-tin bonds is observed. In contrast, reactions of the hydridotin derivatives 1 with CHX3 (X = Cl, Br) lead to the quantitative formation of the bis(chloro-or bromostannyl)oligosilanes 5. All compounds were characterized by NMR, IR, MS and elemental analysis. In addition, the triorganotin compound 2i and the hydridotin species 1b have been characterized by X-ray crystallography.

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