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  • 867-27-6 Structure
  • Basic information

    1. Product Name: Metasystox
    2. Synonyms: Demeton methyl;Metasystox;demeton-O-methyl;O-2-ethylthioethyl O,O-dimethyl phosphorothioate;methyl systox;O,O-DIMETHYLO-ETHYL-2-THIOETHYLETHYLTHIONOPHOSPHATE;METHYLMERCAPTOPHOS;demeton-O-methyl (ISO) O-2-ethylthioethyl O,O-dimethyl phosphorothioate
    3. CAS NO:867-27-6
    4. Molecular Formula: C6H15O3PS2
    5. Molecular Weight: 230.285261
    6. EINECS: 212-758-1
    7. Product Categories: N/A
    8. Mol File: 867-27-6.mol
  • Chemical Properties

    1. Melting Point: <25 °C
    2. Boiling Point: bp0.15 74°
    3. Flash Point: 112.1oC
    4. Appearance: /
    5. Density: d420 1.190
    6. Vapor Pressure: 0.0184mmHg at 25°C
    7. Refractive Index: nD20 1.5063
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: Metasystox(CAS DataBase Reference)
    11. NIST Chemistry Reference: Metasystox(867-27-6)
    12. EPA Substance Registry System: Metasystox(867-27-6)
  • Safety Data

    1. Hazard Codes: T
    2. Statements: 25
    3. Safety Statements: 24-36/37-45
    4. RIDADR: 3018
    5. WGK Germany:
    6. RTECS:
    7. HazardClass: 6.1(b)
    8. PackingGroup: III
    9. Hazardous Substances Data: 867-27-6(Hazardous Substances Data)

867-27-6 Usage

Uses

Demeton Methyl is an organophosphorus pesticides.

Safety Profile

Poison by ingestion, skin contact, inhalation, and intravenous routes. Experimental teratogenic and reproductive effects. When heated to decomposition it emits very toxic fumes of POx and SOx. See also DEMETON-0 + DEMETON-S and other DEMETON entries.

Check Digit Verification of cas no

The CAS Registry Mumber 867-27-6 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 8,6 and 7 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 867-27:
(5*8)+(4*6)+(3*7)+(2*2)+(1*7)=96
96 % 10 = 6
So 867-27-6 is a valid CAS Registry Number.
InChI:InChI=1/C6H15O3PS2/c1-4-12-6-5-9-10(11,7-2)8-3/h4-6H2,1-3H3

867-27-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name demeton-O-methyl

1.2 Other means of identification

Product number -
Other names O-2-ethylthioethyl O,O-dimethyl phosphorothioate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:867-27-6 SDS

867-27-6Relevant articles and documents

Selective Sulfur Oxygenation in Phosphoroamidate, Thionophosphate, and Thiophosphate Agrochemicals by Perfluoro-cis-2,3-dialkyloxaziridine

Terreni, Marco,Pregnolato, Massimo,Resnati, Giuseppe,Benfenati, Emilio

, p. 7981 - 7992 (2007/10/02)

Several organophsophorus agrochemicals 2a-g with thioether, phosphoramidic, phosphorothioic, and phosphorothionic functions were reacted with perfluoro-cis-2-n-butyl-3-n-propyloxaziridine 1.The selective oxygenation of sulfide function to give sulfoxide derivatives 3a-g occured in high yields without overoxidation to sulfone products.Sulfoxides 3a-e were further oxidized under mild conditions to the corresponding sulfones 4a-e.All the products are themselves of interest as analytical environmental standards and their preparation is described in detail.

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