PHOTOLYSIS OF CIS- AND TRANS-2-(3,5-DIMETHOXYPHENYL)CYCLOPENTYL METHANESULFONATE. STEREOELECTRONIC REQUIREMENT FOR PHOTOSOLVOLYSIS
On irradiation in methanol, trans-2-(3,5-dimethoxyphenyl)cyclopentyl methanesulfonate underwent photosolvolysis whereas the cis-isomer did not; thus, for photosolvolysis there exists a trans-requirement of excited aryl group and leaving group.
Jaeger, David A.,Bernhardt, Emily A.
p. 4521 - 4524
(2007/10/02)
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