Germanium(II)-mediated reductive cross-aldol reaction of aldehydes: Synthesis of aldols with diastereocontrolled quaternary carbon centers
anti-Selective synthesis of aldols with quaternary carbon centers was achieved by germanium(II)-mediated reductive cross-aldol reaction of tertiary α-bromo aldehydes with both aromatic and aliphatic aldehydes. One-pot direct reduction and reductive aminat
ALDEHYDE ENOLATE. CROSS ALDOL REACTION via TIN(II) ENOLATE
Tin(II) enolate, formed in situ by the oxidative addition of metallic tin 2-bromo-2-methylpropanal, reacts with aldehydes to give β-hydroxy aldehydes in fairly good yields.
Kato, Jun-ichi,Mukaiyama, Teruaki
p. 1727 - 1728
(2007/10/02)
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