88903-22-4Relevant academic research and scientific papers
Germanium(II)-mediated reductive cross-aldol reaction of aldehydes: Synthesis of aldols with diastereocontrolled quaternary carbon centers
Tanaka, Shin-Ya,Yasuda, Makoto,Baba, Akio
, p. 1720 - 1724 (2007)
anti-Selective synthesis of aldols with quaternary carbon centers was achieved by germanium(II)-mediated reductive cross-aldol reaction of tertiary α-bromo aldehydes with both aromatic and aliphatic aldehydes. One-pot direct reduction and reductive aminat
ALDEHYDE ENOLATE. CROSS ALDOL REACTION via TIN(II) ENOLATE
Kato, Jun-ichi,Mukaiyama, Teruaki
, p. 1727 - 1728 (2007/10/02)
Tin(II) enolate, formed in situ by the oxidative addition of metallic tin 2-bromo-2-methylpropanal, reacts with aldehydes to give β-hydroxy aldehydes in fairly good yields.
