SOME REACTIONS OF TRIS(TRIMETHYLSTANNYL)-AND TETRAKIS(TRIMETHYLSTANNYL)-METHANE
With a variety of electrophilic reagents reaction occurs exclusively at the CH3-Sn bonds of 4C and 3CH.While the inner Sn-C bonds remain intact, methyl groups may be progressively cleaved off, one from each of the trimethylstannyl groups; in the case of bromine a second Me group may be cleaved from each of the SnMe2Br groups.The various products were identified by 1H, 13C and 119Sn MNR spectroscopy.
Hawker, Darryl W.,Wells, Peter R.
p. 37 - 44
(2007/10/02)
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