Preparation and characterization of arylantimony(III) aryloxyacetates ArnSbL3-n
A series of hitherto unreported arylantimony(III)aryloxyacetates of the general formula ArnSbL3-n(n = 1: L = OCOCH 2OC6- H3(CH3)2-2,3 (1); OCOCH(CH3)O C6H4(CH3)-p (2); OCOCH2OC6H5 (3); OCOCH2OC 10H7-β (4); OCOCH2OC6H 4 (CH3)-p (5); OCOCH2OC6H 4 Cl-o (6); OCOCH2OC6H4Cl-p (7); n = 2: L = OCOCH (CH3) OC6H4(CH3)-p (8); OCOCH2O C6H3(CH3) 2-2,3 (9); OCOCH2OC6H4Cl-o (10); have been prepared by the metathesis of ArnSbCl3-n with aryloxyacetic acids. These have been characterized by elemental analysis, IR, 1H NMR spectra and UV spectra. Molar conductance and molecular weight data show them to be nonelectrolyte and having covalent monomeric constitution. These complexes were found to possess moderate to significant antifungal and antibacterial activity. Copyright
Singhal, Kiran,Raj, Prem,Mishra, Rahul,Prakash, Om