Preparation of meso-silylporphyrins via nickel-catalyzed coupling of meso-brominated Ni(II) porphyrins with silylzinc reagents
– In this paper, we developed a technique for the nickel-catalyzed coupling of meso-brominated Ni(II) porphyrins with silylzinc reagents in order to prepare meso-silyl-substituted Ni(II) porphyrins. Porphyrin silylation occurs under mild conditions and ex
Hayashi, Satoshi,Endo, Taiga,Takanami, Toshikatsu
p. 1082 - 1098
(2019/07/31)
New palladium catalysed reactions of bromoporphyrins: Synthesis and crystal structures of nickel(II) complexes of primary 5-aminoporphyrin, 5,5′-bis(porphyrinyl) secondary amine, and 5-hydroxyporphyrin
Primary aminoporphyrin, secondary bis(porphyrinyl)amine and hydroxyporphyrin complexes have been isolated and characterised both spectroscopically and crystallographically from the reaction of 5-bromo-10,15,20-triphenylporphyrinatonickel(II) with hydrazine under palladium catalysis. The Royal Society of Chemistry 2006.
Esdaile, Louisa J.,Senge, Mathias O.,Arnold, Dennis P.
p. 4192 - 4194
(2007/10/03)
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