915719-46-9Relevant academic research and scientific papers
Preparation of meso-silylporphyrins via nickel-catalyzed coupling of meso-brominated Ni(II) porphyrins with silylzinc reagents
Hayashi, Satoshi,Endo, Taiga,Takanami, Toshikatsu
, p. 1082 - 1098 (2019/07/31)
– In this paper, we developed a technique for the nickel-catalyzed coupling of meso-brominated Ni(II) porphyrins with silylzinc reagents in order to prepare meso-silyl-substituted Ni(II) porphyrins. Porphyrin silylation occurs under mild conditions and ex
New palladium catalysed reactions of bromoporphyrins: Synthesis and crystal structures of nickel(II) complexes of primary 5-aminoporphyrin, 5,5′-bis(porphyrinyl) secondary amine, and 5-hydroxyporphyrin
Esdaile, Louisa J.,Senge, Mathias O.,Arnold, Dennis P.
, p. 4192 - 4194 (2007/10/03)
Primary aminoporphyrin, secondary bis(porphyrinyl)amine and hydroxyporphyrin complexes have been isolated and characterised both spectroscopically and crystallographically from the reaction of 5-bromo-10,15,20-triphenylporphyrinatonickel(II) with hydrazine under palladium catalysis. The Royal Society of Chemistry 2006.
