936498-10-1

Basic information

• Product Name: 1-(4-Bromophenyl)isoquinoline
• Synonyms: 1-(4-Bromophenyl)isoquinoline;1-(4-Bromo-phenyl)-isoquinoline
• CAS NO: 936498-10-1
• Molecular Formula: C₁₅H₁₀BrN
• Molecular Weight: 284.1506
• Mol File: 936498-10-1.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-(4-Bromophenyl)isoquinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-Bromophenyl)isoquinoline(936498-10-1)
• EPA Substance Registry System: 1-(4-Bromophenyl)isoquinoline(936498-10-1)

Safety Data

• Hazardous Substances Data: 936498-10-1(Hazardous Substances Data)

Usage

Uses

Used in Material Science:
1-(4-bromophenyl)isoquinoline is used as a building block for the synthesis of more complex molecules, contributing to the development of advanced materials with specific properties.
Used in Medicine:
1-(4-bromophenyl)isoquinoline is used as a functional component in pharmaceuticals, potentially playing a role in the development of new drugs due to its unique chemical structure and properties.
Used in Organic Synthesis:
1-(4-bromophenyl)isoquinoline is used as a key intermediate in various chemical reactions, facilitating the creation of novel organic compounds with diverse applications.
Used in Research and Development:
1-(4-bromophenyl)isoquinoline is used as a valuable target for research and development in the field of organic chemistry, driving innovation and advancements in chemical synthesis and applications.

Upstream product

• 5467-74-3 4-Bromophenylboronic acid 
• 19493-44-8 1-chloroisoquinoline 
• 119-65-3 isoquinoline 
• 106-40-1 4-bromo-aniline 

Downstream Products

• 1220526-60-2 2-[4,4-di(1-isoquinolyl)-[1,1';3',1]-terphenyl-5'-yl]-4,6-di-p-tolyl-1,3,5-triazine 

Relevant articles and documents

Synthesis and properties of hyperbranched fluorescence/phosphorescence hybrid copolymers for white polymer light emitting devices

A series of hyperbranched fluorescence/phosphorescence hybrid copolymers with 9,9-dioctylfluorene and bis(1-phenyl-isoquinoline)(acetylacetonato)iridium(III) (Ir(piq)2acac) as the branches and the three-dimensional structured spiro[3,3]heptane-2,6-dispirofluorene (SDF, 10 mol %) as the core have been synthesized by adjusting the feeding ratios of Ir(piq)2acac (0.02-0.05 mol %). The copolymers showed good thermal and spectral stability, and amorphous film morphology because of the hyperbranched structures. The 2,7-substituted fluorenes of SDF were incorporated into the π-system of the polyfluorene branches, and remained the F?rster resonance energy transfer (FRET) efficiency from fluorene segment to Ir(piq)2acac unit. The copolymers exhibited efficient electroluminescent characters, and white-light emission was achieved in PFSDF-Ir4 (Ir(piq)2acac 0.04 mol %)-based single layer device with CIE coordinates at (0.30, 0.34), a maximum luminance of 6777.3 cd/m2 (at 18.3 V), and a maximum current efficiency of 4.0 cd/A.

Phase-selective modulation of TiO2 for visible light-driven C–H arylation: Tuning of absorption and adsorptivity

To understand and modify TiO2 for organic photoreaction, two points are important: improving light absorption and retaining adsorption sites for organic reagents. Herein, we tuning the absorption and adsorption of TiO2 by introducing

Hyperbranched polymers with aggregation-induced emission property for solution-processed white organic light-emitting diodes

In this work, a new series of hyperbranched polymers of PFTPE-Ir(piq)3-X(X = 1, 5, 10) were designed and synthesized, in which tris(1-phenylisoquinoline)iridium(Ш) (Ir(piq)3) acts as red emission core and PFTPE acts as branches. The

A novel high-efficiency white hyperbranched polymer derived from polyfluorene with green and red iridium(III) complexes as the cores

A new kind of single triple-color hyperbranched polymer PF-Ir(ppy)2(pytzph)m-Ir(piq)2(pytzph)n was designed and synthesized, in which green and red iridium(III) complexes acted as cores and blue polyfluorene acted as backbone. PF-Ir(ppy)2(pytzph)m-Ir(piq)2(pytzph)n (m = 5, n = 5 and m = 25, n = 5) had higher quantum efficiency than PF-Ir(piq)2(pytzph)5. The energy transfer from green core bis(2-phenylpyridine)[3-(2-pyridyl)-5-phenyl-1,2,4-triazole]iridium(III) [Ir(ppy)2(pytzph)] with high triplet energy level (ET = 2.58 eV) to red core bis(1-phenylisoquinolinato)[3-(2-pyridyl)-5-phenyl-1,2,4-triazole]iridium(III) [Ir(piq)2(pytzph)] (ET = 2.12 eV) could realize by intermediate poly(9,9-dioctylfluorene) (PF) segments. A typical single emitting-layer device with the configuration of ITO/PEDOT:PSS (40 nm)/PF-Ir(ppy)2(pytzph)m-Ir(piq)2(pytzph)n (80 nm)/TPBi (40 nm)/LiF (0.8 nm)/Al (100 nm) was fabricated. Among the white polymers, PF-Ir(ppy)2(pytzph)5-Ir(piq)2(pytzph)5 exhibited excellent electroluminescent properties with a Commission Internationale Ed I'eclairage (CIE) coordinate of (0.32, 0.34) and a maximum luminous efficiency of 11.49 cd/A.

Total syntheses of menisporphine and daurioxoisoporphine c enabled by photoredox-catalyzed direct C-H arylation of isoquinoline with aryldiazonium Salt

Isoquinoline alkaloids are attractive natural products due to their diverse chemical structures as well as remarkable bioactivities. Herein, we report the concise total syntheses of two isoquinoline alkaloids, menisporphine and daurioxoisoporphine C, through a mild and efficient photoredox-catalyzed direct C-H arylation of isoquinoline core with aryldiazonium salt. This new strategy is complementary to the conventional isoquinoline synthesis and would provide us a useful means to achieve a more convergent and flexible approach to access diverse isoquinoline structures.