93658-58-3Relevant articles and documents
A highly efficient method for the hydroaminomethylation of long-chain alkenes under aqueous, biphasic conditions
Behr, Arno,Becker, Marc,Reyer, Sebastian
, p. 2438 - 2441 (2010)
The use of salts of secondary and primary amines with different inorganic and organic acids in hydroaminomethylation enables the quantitative conversion of 1-octene with high selectivity for saturated amines. We propose that a cationic rhodium species is formed under the acidic conditions which catalyses the hydrogenation of the enamine or imine formed subsequently. Thus the use of acids and amine salts enables the hydroaminomethylation of long-chain alkenes under aqueous, biphasic conditions with quantitative conversions and short reaction times.
From Internal Olefins to Linear Amines: Ruthenium-Catalyzed Domino Water-Gas Shift/Hydroaminomethylation Sequence
Liu, Jie,Kubis, Christoph,Franke, Robert,Jackstell, Ralf,Beller, Matthias
, p. 907 - 912 (2016/02/18)
A selective ruthenium-catalyzed water-gas shift/hydroformylation of internal olefins and olefin mixtures is reported. This novel domino reaction takes place through a catalytic water-gas shift reaction, subsequent olefin isomerization, followed by hydrofo
Calix[4]arene-diphosphite rhodium complexes in solvent-free hydroaminovinylation of olefins
Monnereau, Laure,Semeril, David,Matt, Dominique
supporting information; experimental part, p. 1670 - 1673 (2010/12/24)
Under solvent-free conditions rhodium complexes containing hemispherical diphosphites based on a calix[4]arene skeleton catalyse efficiently the hydroaminovinylation of α-olefins, thereby leading to high proportions of linear enamines/amines (when startin
Joint Synthesis of Tertiary Unsymmetrical and Symmetrical Aliphatic Amines
Kozlov,Tereshko,Basalaeva,Tarasevich
, p. 1095 - 1098 (2007/10/03)
Tertiary unsymmetrical and symmetrical aliphatic amines were prepared by reaction of higher (C8-C16) and lower (C2-C4) aliphatic alcohols with nitriles containing the same number of carbon atoms as the lower aliphatic alcohols. Reaction conditions ensuring nearly quantitative yields of tertiary amines were determined.