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1-Octene [Standard Material for GC]
Cas No: 111-66-0
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
1-Octene
Cas No: 111-66-0
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Factory Supply Oct-1-ene
Cas No: 111-66-0
No Data 1 1 Ality Chemical Corporation Contact Supplier
1-Octene
Cas No: 111-66-0
USD $ 3.0-4.0 / Kilogram 1 Kilogram 1-10 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
1-OCTENE 111-66-0
Cas No: 111-66-0
USD $ 240.0-240.0 / Kilogram 1 Kilogram 100 Metric Ton/Year Henan Tianfu Chemical Co., Ltd. Contact Supplier
1-Octene
Cas No: 111-66-0
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 500 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
1-Octene 111-66-0
Cas No: 111-66-0
USD $ 100.0-150.0 / Kilogram 1 Kilogram 1000 Metric Ton/Day Wuhan Monad Medicine Tech Co.,LTD Contact Supplier
1-Octene CAS NO.111-66-0
Cas No: 111-66-0
No Data 10 Gram 500 Kilogram/Month Changchun Artel lmport and Export trade company Contact Supplier
1-OCTENE CAS NO.111-66-0
Cas No: 111-66-0
USD $ 100.0-100.0 / Kilogram 1 Kilogram 1000 Metric Ton/Month Metric Ton/Day Hebei Guanlang Biotechnology Co., Ltd. Contact Supplier
1-Octene
Cas No: 111-66-0
No Data No Data 5 Hangzhou J&H Chemical Co., Ltd. Contact Supplier

111-66-0 Usage

InChI:InChI=1/C8H16/c1-3-5-7-8-6-4-2/h3H,1,4-8H2,2H3

111-66-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A11146)  1-Octene, 97+%    111-66-0 500ml 347.0CNY Detail
Alfa Aesar (A11146)  1-Octene, 97+%    111-66-0 2500ml 865.0CNY Detail
Sigma-Aldrich (74900)  1-Octene  analytical standard 111-66-0 74900-5ML 590.85CNY Detail
Sigma-Aldrich (74900)  1-Octene  analytical standard 111-66-0 74900-50ML 3,402.36CNY Detail
Supelco (442274)  1-Octene  analytical standard 111-66-0 000000000000442274 234.00CNY Detail

111-66-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name oct-1-ene

1.2 Other means of identification

Product number -
Other names 1-OCTENE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:111-66-0 SDS

111-66-0Synthetic route

n-octyne
629-05-0

n-octyne

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With zirconocene dichloride; tert-butylmagnesium chloride; water Product distribution; multistep reaction; other hydrozirconation agents; other substrates;100%
With hydrogen In ethanol at 20℃; under 760.051 Torr; for 2.5h;95%
With 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine cobalt(II) dichloride; diethoxymethylane; sodium triethylborohydride In neat (no solvent) at -78 - 40℃; for 1h;95%
(S)-2-octyl chloroformate
191331-78-9

(S)-2-octyl chloroformate

A

trans-2-Octene
13389-42-9

trans-2-Octene

B

oct-1-ene
111-66-0

oct-1-ene

C

(R)-2-chlorooctane
18651-57-5

(R)-2-chlorooctane

Conditions
ConditionsYield
With hexabutylguanidinium chloride In neat (no solvent) for 10h;A n/a
B n/a
C 100%
octanol
111-87-5

octanol

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide In ethyl acetate at 0℃; for 3h;97%
With aluminum oxide at 350℃;
With fired clay fragments at 450 - 500℃;
1-bromo-octane
111-83-1

1-bromo-octane

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With potassium hydroxide; triisopropylsilanol In N,N-dimethyl-formamide Ambient temperature;97%
With 3-(tert-Butylamino)-1,1,1,5,5,5-hexakis(dimethylamino)-3-<amino>-1λ5,3λ5,5λ5-1,4-triphosphazadiene In tetrahydrofuran; xylene for 6h; Ambient temperature;96%
With lithium diisopropylamide at 0℃; Kinetics;87%
n-octyne
629-05-0

n-octyne

A

octane
111-65-9

octane

B

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With hydrogen In hexane at 40℃; under 760.051 Torr; for 6h;A 3%
B 97%
With triisobutylaluminum; zirconocene dichloride In benzene for 0.333333h;A 44%
B 51%
With hydrogen In cyclohexane at 150℃; under 75007.5 Torr; for 48h; Autoclave; Glovebox;A 43%
B 47%
2-octyl chloroformate

2-octyl chloroformate

A

trans-2-Octene
13389-42-9

trans-2-Octene

B

oct-1-ene
111-66-0

oct-1-ene

C

2-chlorooctane
628-61-5

2-chlorooctane

Conditions
ConditionsYield
With hexabutylguanidinium chloride at 100℃; for 5h; Yields of byproduct given;A n/a
B n/a
C 97%
nonanoic acid
112-05-0

nonanoic acid

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With nickel(II) iodide; 1,1,3,3-Tetramethyldisiloxane; copper(II) bis(trifluoromethanesulfonate); triphenylphosphine In neat (no solvent) at 190℃; for 16h; Reagent/catalyst; Sealed tube; Schlenk technique; Inert atmosphere;94%
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)nickel (0); 2,2-dimethylpropanoic anhydride; potassium iodide at 180 - 190℃; for 2h; Inert atmosphere; Glovebox;78%
With sodium persulfate; sulfuric acid; silver nitrate; copper(II) sulfate 1.) water, reflux, 2.) 5 min, reflux; Yield given. Multistep reaction;
1-hexene
592-41-6

1-hexene

octane
111-65-9

octane

hexane
110-54-3

hexane

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
cobalt(II) naphthenate In nonane Product distribution / selectivity;93.1%
methanol
67-56-1

methanol

1-bromo-octane
111-83-1

1-bromo-octane

A

1-methoxyoctane
929-56-6

1-methoxyoctane

B

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With potassium hydroxide; Aliquat 336 at 20℃; for 20h;A 92%
B 7%
1-bromo-octane
111-83-1

1-bromo-octane

potassium ethoxide
917-58-8

potassium ethoxide

A

ethyl octyl ether
929-61-3

ethyl octyl ether

B

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With Aliquat 336 at 20℃; for 20h;A 92%
B 5%
2-(phenylsulfonyl)-1-(trimethylsilyl)octane
84363-56-4

2-(phenylsulfonyl)-1-(trimethylsilyl)octane

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran for 0.666667h; Heating;92%
heptanal
111-71-7

heptanal

(lithiomethyl)dimesitylborane

(lithiomethyl)dimesitylborane

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With trifluoroacetic anhydride91%
ethene
74-85-1

ethene

A

1-hexene
592-41-6

1-hexene

B

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With CrCl2(tetrahydrofuran)2; N,N'-bis(diphenylphosphino)-N,N'-dimethylpropane-1,3-diamine In methyl cyclohexane at 80℃; under 30003 Torr; for 0.5h; Inert atmosphere;A 9%
B 91%
bis(2-(decylthio)ethyl)amine; chromium chloride In toluene at 90℃; under 33753.4 Torr; for 0.502778 - 0.527778h; Product distribution / selectivity;A 90.85%
B 0.5%
chromium(III)2-ethylhexanoate; trimethylaluminum; N-[bis(2-methoxyphenyl)phosphino]-P,P-bis(2-methoxyphenyl)-N-methylphosphinous amide In methyl cyclohexane; toluene at 60℃; under 36003.6 - 37503.8 Torr; for 0.175h; Product distribution / selectivity;A 89.7%
B 8.5%
1,2-octandiol
1117-86-8

1,2-octandiol

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With formic acid at 20 - 240℃; Inert atmosphere;91%
With methyltrioxorhenium(VII); sodium sulfite at 150℃; for 20h; sealed tube;60 %Chromat.
With 15-crown-5; tetrabutylammonium perrhenate; sodium sulfite In benzene at 150 - 160℃; for 100h; regiospecific reaction;68 %Chromat.
rac-octan-2-ol
4128-31-8

rac-octan-2-ol

A

trans-2-Octene
13389-42-9

trans-2-Octene

B

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
at 375℃; under 760.051 Torr; for 0.7h; Reagent/catalyst;A 5.9%
B 90.1%
With copper(II) sulfate In neat (no solvent) at 180℃; under 660 Torr; for 5h; Yield given;
1-Chlorooctane
111-85-3

1-Chlorooctane

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With lithium diisopropylamide In tetrahydrofuran; hexane at -78℃;89%
Multi-step reaction with 2 steps
1: 1.) sodium hydride / 1.) DMF, 20 deg C, 1 h, 2.) 80 deg C, 18 h
2: 1.) NaH / 1.) DMF, 1 h, 2.) 70 deg C, 6 h
View Scheme
Multi-step reaction with 2 steps
1: sodium hydride, trifluoroacetamide / dimethylformamide / 18 h / 80 °C
2: 1.) NaH / 1.) DMF, 1 h, 2.) 70 deg C, 6 h
View Scheme
Multi-step reaction with 2 steps
1: potassium iodide / methanol / Irradiation
2: methanol / Irradiation
View Scheme
heptanal
111-71-7

heptanal

C4H11Cl3GeTi
81454-93-5

C4H11Cl3GeTi

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
In diethyl ether for 15h; from 0 degC to 20 degC;88%
1-bromo-octane
111-83-1

1-bromo-octane

A

1-Fluoro-octane
463-11-6

1-Fluoro-octane

B

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With tetrabutylammomium bromide; cesium fluoride for 1h; Heating;A 88%
B 9.4 % Chromat.
With C12H35N7P2*FH In tetramethylurea; 1,3,5-trimethyl-benzene at 120℃; for 0.416667h; Inert atmosphere;A 72%
B 14%
With 1,1,1-trifluoro-2-(2,2,2-trifluoroethoxy)ethane; 2,2-Dimethylpropyltrimethylammonium fluoride at 25℃;A 71%
B 29%
1-Iodooctane
629-27-6

1-Iodooctane

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With lithium diisopropylamide In tetrahydrofuran; hexane at -78℃;88%
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃; for 14h;87%
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride at 0 - 20℃; Inert atmosphere;87%
1-octyl p-toluenesulfonate
3386-35-4

1-octyl p-toluenesulfonate

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃; for 13h;88%
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride at 0 - 20℃; Inert atmosphere;88%
2-(but-3-en-1-yl)-2-methyl-1,3-dioxolane
20449-21-2

2-(but-3-en-1-yl)-2-methyl-1,3-dioxolane

tetradec-7-ene
10374-74-0

tetradec-7-ene

A

oct-1-ene
111-66-0

oct-1-ene

B

2-((E)-Dec-3-enyl)-2-methyl-[1,3]dioxolane

2-((E)-Dec-3-enyl)-2-methyl-[1,3]dioxolane

Conditions
ConditionsYield
aluminum oxide; tetramethylstannane; rhenium(VII) oxide In chlorobenzene at 25℃; for 3h; Yields of byproduct given;A n/a
B 87.8%
1-bromo-octane
111-83-1

1-bromo-octane

sodium methylate
124-41-4

sodium methylate

A

1-methoxyoctane
929-56-6

1-methoxyoctane

B

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With Aliquat 336 at 20℃; for 20h;A 87%
B 13%
1-bromo-octane
111-83-1

1-bromo-octane

sodium ethanolate
141-52-6

sodium ethanolate

A

ethyl octyl ether
929-61-3

ethyl octyl ether

B

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With potassium hydroxide; Aliquat 336 at 20℃; for 20h;A 86%
B 10%
di-2-octyl phenylphosphonate
107465-90-7

di-2-octyl phenylphosphonate

A

2-octene
111-67-1

2-octene

B

oct-1-ene
111-66-0

oct-1-ene

C

phenylphosphonate
1571-33-1

phenylphosphonate

Conditions
ConditionsYield
With Amberlite 200C In dichloromethane at 40℃; for 72h; Product distribution;A n/a
B n/a
C 85%
(E) 2-iodo-1-chloroethylene
28540-81-0

(E) 2-iodo-1-chloroethylene

n-octyne
629-05-0

n-octyne

A

oct-1-ene
111-66-0

oct-1-ene

B

(1E,3E)-1-chloro-1,3-decadiene
96251-47-7

(1E,3E)-1-chloro-1,3-decadiene

Conditions
ConditionsYield
Stage #1: n-octyne With diisobutylaluminium hydride In n-heptane at 50℃; for 4h;
Stage #2: With indium(III) chloride In tetrahydrofuran; n-heptane at 0℃; for 0.5h;
Stage #3: (E) 2-iodo-1-chloroethylene With trifuran-2-yl-phosphane; Cl2Pd[bis(2-diphenylphosphinophenyl)ether]; diisobutylaluminium hydride In tetrahydrofuran; hexane; n-heptane at 0℃; for 4h;
A 4 % Spectr.
B 85%
2-octyl mesylate
924-80-1

2-octyl mesylate

A

2-fluorooctane
407-95-4

2-fluorooctane

B

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydrogensulfate; triphenyltinfluoride In acetonitrile at 85℃; for 10h;A 83%
B 12%
1-fluoropentane
592-50-7

1-fluoropentane

allyl-trimethyl-silane
762-72-1

allyl-trimethyl-silane

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With 2C24BF20(1-)*C21H16N3P(2+) In dichloromethane at 55℃; for 24h; Reagent/catalyst; Inert atmosphere;83%
(R)-2-octanol trimethylsilyl ether
51003-20-4

(R)-2-octanol trimethylsilyl ether

A

cis-2-octene
7642-04-8

cis-2-octene

B

trans-2-Octene
13389-42-9

trans-2-Octene

C

oct-1-ene
111-66-0

oct-1-ene

D

(S)-(+)-2-fluorooctane

(S)-(+)-2-fluorooctane

Conditions
ConditionsYield
With diethylamino-sulfur trifluoride In dichloromethane at -78 - -20℃; for 10h;A n/a
B n/a
C n/a
D 82%
(E)-1-bromo-2-iodoethylene
56798-08-4

(E)-1-bromo-2-iodoethylene

n-octyne
629-05-0

n-octyne

A

oct-1-ene
111-66-0

oct-1-ene

B

(7E,9E)-hexadeca-7,9-diene
71686-99-2

(7E,9E)-hexadeca-7,9-diene

C

(1E,3E)-1-bromo-1,3-decadiene
174365-91-4

(1E,3E)-1-bromo-1,3-decadiene

Conditions
ConditionsYield
Stage #1: n-octyne With diisobutylaluminium hydride In n-heptane at 50℃; for 4h;
Stage #2: With indium(III) chloride In tetrahydrofuran; n-heptane at 0℃; for 0.5h;
Stage #3: (E)-1-bromo-2-iodoethylene With trifuran-2-yl-phosphane; Cl2Pd[bis(2-diphenylphosphinophenyl)ether]; diisobutylaluminium hydride In tetrahydrofuran; hexane; n-heptane at 0℃; for 4h;
A 7%
B 2%
C 82%
oct-1-ene
111-66-0

oct-1-ene

triphenylstannane
892-20-6

triphenylstannane

n-octyltriphenylstannane
23895-44-5

n-octyltriphenylstannane

Conditions
ConditionsYield
at 80-100 °C;;100%
at 80-100 °C;;100%
In neat (no solvent) other Radiation; under Ar; (60)Co-irradiation; 1.5:1 molar ratio (olefine:Sn-compound) ;25°C; GLC;74%
oct-1-ene
111-66-0

oct-1-ene

octane
111-65-9

octane

Conditions
ConditionsYield
With hydrogen; In dichloromethane at 65℃; for 15h; same yield with a similar catalyst; Pressure (range begins): 120 ;100%
With {(η6-C6H6)Ru(NCCH3)3}{BF4}2; water; hydrogen In benzene at 90℃; under 30400 Torr; for 4h;100%
With hydrogen; In dichloromethane at 65℃; for 15h; Product distribution; other catalyst, other substrates; Pressure (range begins): 120 ;100%
oct-1-ene
111-66-0

oct-1-ene

1,2-octandiol
1117-86-8

1,2-octandiol

Conditions
ConditionsYield
With poly{[CuBa(pyridine-2,5-dicarboxylate)2(H2O)5]*H2O}; dihydrogen peroxide In acetonitrile at 60℃; for 6h; Catalytic behavior; Reagent/catalyst;100%
With dmap; osmium(VIII) oxide; 4-methylmorpholine N-oxide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate In water; tert-butyl alcohol at 20℃; for 16h;99%
With 4-methylmorpholine N-oxide; dendritic osmium catalyst In hexane; acetonitrile; tert-butyl alcohol at 20℃; for 36h;98%
oct-1-ene
111-66-0

oct-1-ene

1,2-dichlorooctane
21948-46-9, 72778-28-0

1,2-dichlorooctane

Conditions
ConditionsYield
With tetraethylammonium trichloride In dichloromethane100%
With chlorine In chloroform at 20℃; for 1.5h;97%
With oxone||potassium monopersulfate triple salt; potassium chloride; N-(n-butyl)-2-methylbenzamide In dichloromethane; water at 20℃; for 0.25h;91%
oct-1-ene
111-66-0

oct-1-ene

1,2-Epoxyoctane
2984-50-1

1,2-Epoxyoctane

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid; iron(III) perchlorate In acetonitrile at -10℃; for 0.0833333h;100%
With 3-chloro-benzenecarboperoxoic acid; (Cl8TPP)FeIII(ClO4) In acetonitrile at -10℃; for 0.0833333h; Product distribution; invetigation of the iron(III) perchlorate-catalyzed epoxidation of olefins and oxidative cleavage of diols by m-chloroperbenzoic acid and pentafluoroiodobenzene;100%
With oxygen; isobutyraldehyde In acetonitrile at 60℃; for 18h;99%
oct-1-ene
111-66-0

oct-1-ene

Triethoxysilane
998-30-1

Triethoxysilane

triethoxy(octyl)silane
2943-75-1

triethoxy(octyl)silane

Conditions
ConditionsYield
at 90℃; for 5h; Inert atmosphere;100%
at 90℃; for 5h; Inert atmosphere;100%
With graphene nanoplates-supported platinum nanoparticles In neat (no solvent) at 80℃; for 2h; Catalytic behavior;99%
oct-1-ene
111-66-0

oct-1-ene

Diethyl phosphonate
762-04-9, 123-22-8

Diethyl phosphonate

diethyl octylphosphonate
1068-07-1

diethyl octylphosphonate

Conditions
ConditionsYield
With triethyl borane; oxygen In cyclohexane at 20℃;100%
at 30℃; for 17h; (γ-irradiation);
oct-1-ene
111-66-0

oct-1-ene

carbon monoxide
201230-82-2

carbon monoxide

nonan-1-al
124-19-6

nonan-1-al

Conditions
ConditionsYield
With 2-pyridylpropylimine rhodium(I)chlorocarbonyl; hydrogen In toluene at 95℃; Catalytic behavior; Reagent/catalyst; Pressure; Temperature; Autoclave; chemoselective reaction;100%
With hydrogen In dichloromethane at 45℃; under 51716.2 Torr; for 16h; Autoclave; Inert atmosphere; Green chemistry; regioselective reaction;100%
With hydrogen In cyclohexane at 120℃; under 37503.8 Torr; for 4h; Autoclave;99%
oct-1-ene
111-66-0

oct-1-ene

thexylchloroborane * dimethylsulfide
75067-06-0

thexylchloroborane * dimethylsulfide

A

octanol
111-87-5

octanol

B

rac-octan-2-ol
4128-31-8

rac-octan-2-ol

C

2,3-dimethylbutan-2-ol
594-60-5

2,3-dimethylbutan-2-ol

Conditions
ConditionsYield
With methanol; dihydrogen peroxide Product distribution; different solvents; other olefins;A 99.2%
B 0.8%
C 100%
oct-1-ene
111-66-0

oct-1-ene

oenanthic acid
111-14-8

oenanthic acid

Conditions
ConditionsYield
With dihydrogen peroxide; 6-molybdo-6-tungstophosphoric acid/Al/C In tert-butyl alcohol at 60℃; for 4h;100%
With [Me(n-Oct)3N]3{PO4[WO(O2)2]4}; dihydrogen peroxide In water; 1,2-dichloro-ethane at 95℃; for 5h; Catalytic behavior; Reagent/catalyst; Temperature; Concentration; Reflux; Green chemistry;97%
With jones reagent; osmium(VIII) oxide In water; acetone for 20h; Ambient temperature;85%
oct-1-ene
111-66-0

oct-1-ene

Trichloroacetyl chloride
76-02-8

Trichloroacetyl chloride

2,2-Dichloro-3-hexyl-cyclobutanone
217805-08-8

2,2-Dichloro-3-hexyl-cyclobutanone

Conditions
ConditionsYield
With zinc In diethyl ether at 15 - 20℃; for 1.5h; sonication;100%
With zinc/copper couple; trichlorophosphate In diethyl ether Reflux;
With zinc-copper couple; trichlorophosphate In diethyl ether Reflux; Inert atmosphere;
With zinc/copper couple; trichlorophosphate In diethyl ether at 0℃; Inert atmosphere; Reflux;
oct-1-ene
111-66-0

oct-1-ene

1,1,1,3,5,5,5-heptamethyltrisiloxan
1873-88-7

1,1,1,3,5,5,5-heptamethyltrisiloxan

3-n-octyl-1,1,1,3,5,5,5-heptamethyltrisiloxane
17955-88-3

3-n-octyl-1,1,1,3,5,5,5-heptamethyltrisiloxane

Conditions
ConditionsYield
With tetradecyl(tributyl)phosphonium bis(trifluoromethylsulfonyl)amide; C24H20Cl2P2Pt at 100℃; for 1h; Reagent/catalyst;100%
With tetradecyl(tributyl)phosphonium bis(trifluoromethylsulfonyl)amide; bis(cyclooctadiene (μ-silyloxytrimethyl) rhodium(I)) at 110℃; for 1h; Catalytic behavior; Reagent/catalyst; Time;100%
With nickel 2-ethylhexanoate; 1,4-bis(2,6-diisopropylphenyl)-2,3-dimethyl-1,4-diazabuta-1,3-diene In neat (no solvent) at 23℃; for 6h; regioselective reaction;99%
oct-1-ene
111-66-0

oct-1-ene

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

4,4,5,5-tetramethyl-2-octyl-[1,3,2]dioxaborolane
66217-56-9

4,4,5,5-tetramethyl-2-octyl-[1,3,2]dioxaborolane

Conditions
ConditionsYield
With sodium triethylborohydride at 23℃; for 3h; Catalytic behavior; Reagent/catalyst; Inert atmosphere;100%
Wilkinson's catalyst In dichloromethane 25°C, 10 min;99%
With chlorocarbonylbis(triphenylphosphine)rhodium(I) In dichloromethane at 0 - 20℃; for 1.83333h; Inert atmosphere;99%
oct-1-ene
111-66-0

oct-1-ene

n-octylphosphonic acid
4724-48-5

n-octylphosphonic acid

Conditions
ConditionsYield
With hypophosphorous acid; palladium; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In water; N,N-dimethyl-formamide at 110℃; for 24h;100%
With tris-(dibenzylideneacetone)dipalladium(0); hypophosphorous acid; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; oxygen In N,N-dimethyl-formamide at 110℃; for 20h;
Multi-step reaction with 2 steps
1: tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene / tetrahydrofuran / 9 h / 70 °C
2: sodium hydroxide; potassium permanganate / water / 5 h / 15 °C / Cooling with ice
View Scheme
oct-1-ene
111-66-0

oct-1-ene

tri-n-butyl-tin hydride
688-73-3

tri-n-butyl-tin hydride

tributyl(octyl)stannane
14775-14-5

tributyl(octyl)stannane

Conditions
ConditionsYield
With diisobutylaluminium hydride 75-80°C;;100%
With (iso-C4H9)2AlH 75-80°C;;100%
With diisobutylaluminium hydride 75-80°C;;100%
Phenylselenyl chloride
5707-04-0

Phenylselenyl chloride

oct-1-ene
111-66-0

oct-1-ene

C14H21ClSe
1401238-31-0

C14H21ClSe

Conditions
ConditionsYield
In dichloromethane at 20℃; for 4h; Inert atmosphere;100%
Conditions
ConditionsYield
With titanium(IV) isopropylate; Pentafluorobenzoic acid; C32H22F10N2O2; dihydrogen peroxide In water; 1,2-dichloro-ethane at 20℃; for 45h; Inert atmosphere; enantioselective reaction;100%
With titanium(IV) isopropylate; C46H40N2O2; dihydrogen peroxide In dichloromethane; water; 1,2-dichloro-ethane at 20℃; for 100h; Reagent/catalyst; Inert atmosphere;82%
With oxygen; isobutyraldehyde In acetonitrile at 25℃; for 8h; Catalytic behavior; Green chemistry; enantioselective reaction;70 %Chromat.
oct-1-ene
111-66-0

oct-1-ene

dimethylsulfide borane complex
13292-87-0

dimethylsulfide borane complex

trioctylborane
3248-78-0

trioctylborane

Conditions
ConditionsYield
In Petroleum ether at -10 - 0℃; for 1h; Inert atmosphere;100%
at 0 - 20℃; for 3h; Inert atmosphere; Further stages;
In tetrahydrofuran at 20℃; for 1h; Cooling with ice;
In diethyl ether Inert atmosphere; Reflux;
oct-1-ene
111-66-0

oct-1-ene

phenylsilane
694-53-1

phenylsilane

octan-2-yl(phenyl)silane

octan-2-yl(phenyl)silane

Conditions
ConditionsYield
With MesPDI; cobalt(II) stearate In tetrahydrofuran at 60℃; for 5h; Reagent/catalyst;100%
With C22H31Cl2CoN2P In neat (no solvent) at 60℃; for 24h; Reagent/catalyst; Temperature; Sealed tube; Inert atmosphere; regioselective reaction;92%
With 2,6-bis[1-(2,4,6-trimethylimino)ethyl]pyridine; C10H14CoO5 In toluene at 60℃; for 24h; Reagent/catalyst; Temperature; regioselective reaction;91%
With 2,6-bis[1-(2,4,6-trimethylimino)ethyl]pyridine; cobalt(II) tetrafluoroborate hexahydrate In tetrahydrofuran at 20℃; for 4h; Catalytic behavior; Reagent/catalyst; regioselective reaction;72 %Spectr.
oct-1-ene
111-66-0

oct-1-ene

triisobutylaluminum
100-99-2

triisobutylaluminum

trioctylaluminum
1070-00-4

trioctylaluminum

Conditions
ConditionsYield
at 110℃; Inert atmosphere; Schlenk technique;100%
oct-1-ene
111-66-0

oct-1-ene

bis-(2-bromooctyl)selenide

bis-(2-bromooctyl)selenide

Conditions
ConditionsYield
With selenium dibromide In tetrachloromethane at -20 - 20℃; for 18h; regioselective reaction;100%
With selenium dibromide In chloroform at 20 - 25℃; for 18h; regioselective reaction;95%
Stage #1: oct-1-ene With selenium(IV) oxide; hydrogen bromide In diethyl ether; water at 0 - 25℃; for 0.5h;
Stage #2: With sodium metabisulfite In benzene at 5 - 25℃; for 2h;
84%
oct-1-ene
111-66-0

oct-1-ene

trichloro(2-chlorooctyl)-λ4-tellane

trichloro(2-chlorooctyl)-λ4-tellane

Conditions
ConditionsYield
With tellurium tetrachloride In chloroform at 20 - 25℃; for 20h; regioselective reaction;100%
methanol
67-56-1

methanol

oct-1-ene
111-66-0

oct-1-ene

trichloro(2-methoxyoctyl)-λ4-tellane

trichloro(2-methoxyoctyl)-λ4-tellane

Conditions
ConditionsYield
With tellurium tetrachloride In chloroform at 20 - 25℃; for 20h; regioselective reaction;100%
methanol
67-56-1

methanol

oct-1-ene
111-66-0

oct-1-ene

tribromo(2-methoxyoctyl)-λ4-tellane

tribromo(2-methoxyoctyl)-λ4-tellane

Conditions
ConditionsYield
With tellurium(IV) tetrabromide at 55 - 60℃; for 6h; regioselective reaction;100%
oct-1-ene
111-66-0

oct-1-ene

bis-(2-chlorooctyl)selenide

bis-(2-chlorooctyl)selenide

Conditions
ConditionsYield
With selenium(II) chloride In chloroform at -60 - 20℃; for 18h; regioselective reaction;100%
Stage #1: oct-1-ene With hydrogenchloride; selenium(IV) oxide In diethyl ether; water at 0 - 25℃; for 7h;
Stage #2: With sodium metabisulfite In benzene at 5 - 25℃; for 2h;
80%
ethanol
64-17-5

ethanol

oct-1-ene
111-66-0

oct-1-ene

trichloro(2-ethoxyoctyl)-λ4-tellane

trichloro(2-ethoxyoctyl)-λ4-tellane

Conditions
ConditionsYield
Stage #1: oct-1-ene With tellurium tetrachloride In chloroform at 0 - 20℃; for 14h;
Stage #2: ethanol In chloroform for 5h; Reflux;
100%
ethyl methyl disulfide
20333-39-5

ethyl methyl disulfide

oct-1-ene
111-66-0

oct-1-ene

1-ethylsulfanyl-2-methylsulfanyl-octane

1-ethylsulfanyl-2-methylsulfanyl-octane

Conditions
ConditionsYield
for 2h; UV-irradiation; cooling;99.6%
oct-1-ene
111-66-0

oct-1-ene

Triethoxysilane
998-30-1

Triethoxysilane

β-octylltriethoxysilane
1233710-95-6

β-octylltriethoxysilane

Conditions
ConditionsYield
With Wilkinson's catalyst at 80℃; for 6h; Reagent/catalyst;99.3%
With graphite oxide-supported Karstedt catalyst at 60℃; for 1h;
With rhodium(III) chloride trihydrate; diphenyl(3-triethylsilylphenyl)phosphine at 90℃; for 5h; Inert atmosphere; Schlenk technique;
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