Radical-Nucleophilic Substitution (SRN1) Reactions. Part 2. Preparation and Reactions of α-Nitrosulphides
A range of α-nitrosulphides have been prepared by oxidative addition of thiolate anion to the anion of 2-nitropropane, SN2 attack of the anion of 2-nitropropane on symmetrical disulphides, and SRN1 reaction of 2-substituted-2-nitropropanes with thiolate anions.The α-nitrosulphides undergo SRN1 substitution with the anion of 2-nitropropane, and SRN1 substitution or redox reactions with thiolate anions.The electron spin resonance (e.s.r.) spectrum of the radical-anion of 1-methyl-1-nitroethyl pyrimidin-2-yl sulphide has been observed.
Bowman, W. Russell,Rakshit, Devajvoti,Valmas, Michael D.
p. 2327 - 2336
(2007/10/02)
EFFECTS OF METHANOL SOLVATION ON THE NUCLEOPHILIC REACTIONS OF THIOLATES WITH 2-SUBSTITUTED-2-NITROPROPANES
Methanol solvation prevents SRN1 substitution in the reaction of Me2C(X)NO2 with thiolates and favours an alternative redox reaction to yield disulphide and nitronate.
Al-Khalil, Suleiman I.,Bowman, W. Russell
p. 461 - 464
(2007/10/02)
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