95106-85-7

Upstream product

• 594-71-8 2-chloro-2-nitro-propane 
• 13327-62-3 2-mercaptopyridine sodium salt 
• 5447-97-2 2-bromo-2-nitropropane 
• 29878-59-9 thiolate of 2-mercaptopyridine 
• 595-49-3 2,2-dinitropropane 
• 2127-03-9 2,2'-dipyridyldisulphide 

Downstream Products

• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 52755-34-7 1-methyl-1-nitroethyl p-chlorophenyl sulphide 

Relevant academic research and scientific papers

Radical-Nucleophilic Substitution (SRN1) Reactions. Part 2. Preparation and Reactions of α-Nitrosulphides

A range of α-nitrosulphides have been prepared by oxidative addition of thiolate anion to the anion of 2-nitropropane, SN2 attack of the anion of 2-nitropropane on symmetrical disulphides, and SRN1 reaction of 2-substituted-2-nitropropanes with thiolate anions.The α-nitrosulphides undergo SRN1 substitution with the anion of 2-nitropropane, and SRN1 substitution or redox reactions with thiolate anions.The electron spin resonance (e.s.r.) spectrum of the radical-anion of 1-methyl-1-nitroethyl pyrimidin-2-yl sulphide has been observed.

EFFECTS OF METHANOL SOLVATION ON THE NUCLEOPHILIC REACTIONS OF THIOLATES WITH 2-SUBSTITUTED-2-NITROPROPANES

Methanol solvation prevents SRN1 substitution in the reaction of Me2C(X)NO2 with thiolates and favours an alternative redox reaction to yield disulphide and nitronate.