THE SYNTHESIS OF AMINO ACIDS BY REACTION OF AN ELECTROPHILIC GLYCINE CATION EQUIVALENT WITH CARBON NUCLEOPHILES
Acetate 1, a glycine cation equivalent, is reacted with organocopper reagents to yield products 2 which can readily be converted to the higher amino acids.This method provides access to aryl-substituted amino acids as well as amino acids containing a β-tertiary carbon.
O'Donnell, Martin J.,Falmagne, Jean-Bernard
p. 699 - 702
(2007/10/02)
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