100134-03-0

Basic information

• Product Name: Phosphonic acid, [4-(1,1-dimethylethyl)phenyl]-
• CAS NO: 100134-03-0
• Molecular Formula: C10H15O3P
• Molecular Weight: 214.201
• Mol File: 100134-03-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, [4-(1,1-dimethylethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, [4-(1,1-dimethylethyl)phenyl]-(100134-03-0)
• EPA Substance Registry System: Phosphonic acid, [4-(1,1-dimethylethyl)phenyl]-(100134-03-0)

Safety Data

• Hazardous Substances Data: 100134-03-0(Hazardous Substances Data)

Upstream product

• 769-92-6 4-tert-Butylaniline 
• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 60692-79-7 (4-(tert-butyl)phenyl)dichlorophosphine 
• 60692-86-6 4-tert.-Butylphenyl-(bis-diethylamino)-phosphin 
• 13172-88-8 4-tert.-Butylphenyl-phosphorige Saeure-dichlorid 
• 10294-56-1 phosphorous acid 
• 72596-31-7 diethyl (p-(tert-butyl)phenyl)phosphonate 

Downstream Products

• 128333-50-6 (4-tert-Butyl-phenyl)-phosphonic acid monohexyl ester 

Relevant articles and documents

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High nuclearity (octa-, dodeca-, and pentadecanuclear) metal (M = Co II, NiII) phosphonate cages: Synthesis, structure, and magnetic behavior

The synthesis, structural characterization, and magnetic property studies of five new transition metal (M = Co, Ni) phosphonate-based cages are reported. Three substituted phenyl and benzyl phosphonate ligands [RPO3H 2; R1 = p-tert-butylbenzyl, R2 = p-tert-butylphenyl, R3 = 3-chlorobenzyl] were synthesized and employed to seek out high-nuclearity cages. Complexes 1-3 are quasi-isostructural and feature a dodecanuclear metal-oxo core having the general molecular formula of [M12(μ3-OH)4 (O3PR)4(O2CtBu)6 (HO 2CtBu)6(HCO3)6] {M = Co, Ni and R = R1 for 1 (Co12), R2 for 2, 3 (Co12, Ni12)}. The twelve metal centers are arranged at the vertices of a truncated tetrahedron in a manner similar to Keggin ion. Complex 4 is an octanuclear nickel phosphonate cage [Ni8(μ 3-OH)4 (OMe)2(O3PR1) 2 (O2CtBu)6(HO2C tBu)8], and complex 5 represents a pentadecanuclear cobalt phosphonate cage, [Co15(chp)8(chpH) (O3PR 3)8(O2CtBu)6], where chpH = 6-chloro-2-hydroxypyridine. Structural investigation reveals some interesting geometrical features in the molecular cores, which may provide new models in single molecular magnetic materials. Magnetic property measurements of compounds 1-5 indicate the coexistence of both antiferromagnetic and ferromagnetic interactions between magnetic centers for all cages.