769-92-6

Basic information

• Product Name: 4-tert-Butylaniline
• Synonyms: TIMTEC-BB SBB007738;BUTTPARK 44\03-77;BENZENAMINE, 4-(1,1-DIMETHYLETHYL)-;4-TERT-BUTYLANILINE;4-tert-Butylaniline,99%;4-TERT-BUTYL BENZENEAMINE;1-Amino-4-tert-butylbenzene;4-tert-Butylaniline 98%
• CAS NO: 769-92-6
• Molecular Formula: C₁₀H₁₅N
• Molecular Weight: 149.23
• EINECS: 212-215-9
• Product Categories: Drug Intermediates;Aromatics;Amines;Phenyls & Phenyl-Het;C9 to C10;Nitrogen Compounds
• Mol File: 769-92-6.mol
• Article Data: 102

Chemical Properties

• Melting Point: 15-16 °C(lit.)
• Boiling Point: 90-93 °C3 mm Hg(lit.)
• Flash Point: 215 °F
• Appearance: Clear orange-red to brownish/Liquid
• Density: 0.937 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0431mmHg at 25°C
• Refractive Index: n20/D 1.538(lit.)
• Storage Temp.: 0-10°C
• PKA: pK1: 3.78(+1) (25°C)
• Water Solubility: Insoluble in water.
• Sensitive: Light Sensitive
• BRN: 2205786
• CAS DataBase Reference: 4-tert-Butylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-tert-Butylaniline(769-92-6)
• EPA Substance Registry System: 4-tert-Butylaniline(769-92-6)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 2
• Hazardous Substances Data: 769-92-6(Hazardous Substances Data)

Usage

Chemical Properties

clear orange-red to brownish liquid

Uses

4-tert-Butylaniline reacts with formic acid to produce formic acid-(4-tert-butyl-anilide). This reaction could happen in the presence of the solvent of toluene in the condition of heating. 4-tert-Butylaniline is used in the synthesis of 4-tert-Butyl-4?,4?-dinitrotriphenylamine, new triphenylamine-containing diamine monomer and 2-oxopyrimido[4,5-d]pyrimidin-5(6H)-one.

General Description

Schiff base formation reaction between 4-tert-butylaniline and 4-tert-butylbenzaldehyde in ethanol has been carried out using the matrix-assisted laser desorption ionization-chip system.

InChI:InChI=1/C10H15N/c1-10(2,3)8-4-6-9(11)7-5-8/h4-7H,11H2,1-3H3/p+1

Upstream product

• 78-83-1 2-methyl-propan-1-ol 
• 142-04-1 aniline hydrochloride 
• 98-54-4 para-tert-butylphenol 
• 64-10-8 phenyl carbamate 
• 75-65-0 tert-butyl alcohol 
• 98-73-7 4-(1,1-dimethylethyl)benzoic acid 
• 253185-03-4 tert-butylbenzene 
• 35779-04-5 1-tert-butyl-4-iodobenzene 
• 75-28-5 Isobutane 
• 62-53-3 aniline 
• 4627-22-9 bis(4-tert-butylphenyl)amine 
• 937-33-7 N-tert-butylaniline 
• 479533-85-2 1-(4-tert-butylphenyl)-3-phenylthiourea 
• 1102959-05-6 nitrobenzene radical anion sodium salt 

Downstream Products

• 93721-24-5 4-tert-butyl-N,N-bis-(2-hydroxy-ethyl)-aniline 
• 2909-79-7 4-tert-butyl-N,N-dimethylaniline 
• 78015-86-8 1,3-bis(4-(tert-butyl)phenyl)urea 
• 63429-97-0 N-(4-(tert-butyl)phenyl)formamide 
• 68714-39-6 N,N'-bis-(4-tert-butyl-phenyl)-thiourea 
• 4627-22-9 bis(4-tert-butylphenyl)amine 
• 35779-04-5 1-tert-butyl-4-iodobenzene 
• 31951-12-9 4-tert-butyl-3-nitro-phenylamine 
• 4365-63-3 2‐((4‐(tert‐butyl)phenyl)thio)acetic acid 
• 100134-03-0 4-tert-butylphenyl phosphonic acid 
• 20330-45-4 4-tert-butylacetanilide 
• 4572-48-9 N-(4-(tert-butyl)phenyl)naphthalen-1-amine 
• 59238-66-3 N-(4-(tert?butyl)phenyl)benzamide 
• 479533-85-2 1-(4-tert-butylphenyl)-3-phenylthiourea 

Relevant articles and documents

Highly organic phase soluble polyisobutylene-bound cobalt phthalocyanines as recyclable catalysts for nitroarene reduction

A cobalt phthalocyanine (CoMPc) containing covalently linked polyisobutylene (PIB) groups as phase anchors that is both highly soluble in nonpolar organic solvents and phase selectively soluble in a liquid/liquid separation step is shown to be an effective recyclable homogeneous catalyst for nitroarene reduction in a semi-thermomorphic system. Electron-donating and electron-withdrawing substituents in the nitroarene are tolerated in this aniline synthesis and the catalyst is recyclable up to 10 cycles with little leaching and no detectable loss in reactivity after 10 cycles.

Development and Application of Efficient Ag-based Hydrogenation Catalysts Prepared from Rice Husk Waste

The development of strategies for the sustainable management and valorization of agricultural waste is of outmost importance. With this in mind, we report the use of rice husk (RH) as feedstock for the preparation of heterogeneous catalysts for hydrogenation reactions. The catalysts were prepared by impregnating the milled RH with a silver nitrate solution followed by carbothermal reduction. The composition and morphology of the prepared catalysts were fully assessed by IR, AAS, ICP-MS, XPS, XRD and STEM techniques. This novel bio-genic silver-based catalysts showed excellent activity and remarkable selectivity in the hydrogenation of nitro groups in both aromatic and aliphatic substrates, even in the presence of reactive functionalities like halogens, carbonyls, borate esters or nitriles. Recycling experiments showed that the catalysts can be easily recovered and reused multiple times without significant drop in performance and without requiring re-activation.

Method for synthesizing heteroatom- substituted aromatic compound from styrene compound

The invention discloses a method for synthesizing a heteroatom-substituted aromatic compound from a styrene compound, which comprises the following steps of: mixing a styrene compound with a general formula (I) and a heteroatom-containing compound with a general formula (II), and reacting in the presence of an acid additive and an organic solvent to obtain a heteroatom-substituted compound with ageneral formula (III). According to the synthesis method disclosed by the invention, a large amount of styrene compounds are used as raw materials and react to generate aromatic amine or phenol compounds under the action of no metal catalysis; and compared with the traditional aromatic amine and phenol synthesis method, the method has the advantages of high yield, simple conditions, low waste discharge amount, no metal participation, simple reaction equipment, easiness in industrial production and the like.