100256-95-9Relevant articles and documents
Aldol reaction via in situ olefin migration in water
Wang, Mingwen,Li, Chao-Jun
, p. 3589 - 3591 (2002)
In the presence of a catalytic amount of RuCl2(PPh3)3, aldehydes reacted with allyl alcohols to give aldol-type products in water and under an atmosphere of air.
Generation of rhodium enolates via retro-aldol reaction and its application to regioselective aldol reaction
Murakami, Kei,Ohmiya, Hirohisa,Yorimitsu, Hideki,Oshima, Koichiro
, p. 2388 - 2390 (2008/09/18)
Retro-aldol reactions of β-hydroxy ketones take place under rhodium catalysis, leading to regioselective formation of the corresponding rhodium enolates. The enolates react with aldehydes in situ to afford the corresponding aldol adducts in high yields.