100414-89-9

Basic information

• Product Name: 6-(3,7-Dimethylocta-2E,6-dienyl)-3-(2-methylpropyloxy)-2-cyclohexen-1-one
• Synonyms: 6-(3,7-Dimethylocta-2E,6-dienyl)-3-(2-methylpropyloxy)-2-cyclohexen-1-one
• CAS NO: 100414-89-9
• Molecular Weight: 304.473
• Mol File: 100414-89-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 6-(3,7-Dimethylocta-2E,6-dienyl)-3-(2-methylpropyloxy)-2-cyclohexen-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 6-(3,7-Dimethylocta-2E,6-dienyl)-3-(2-methylpropyloxy)-2-cyclohexen-1-one(100414-89-9)
• EPA Substance Registry System: 6-(3,7-Dimethylocta-2E,6-dienyl)-3-(2-methylpropyloxy)-2-cyclohexen-1-one(100414-89-9)

Safety Data

• Hazardous Substances Data: 100414-89-9(Hazardous Substances Data)

Upstream product

• 504-02-9 1,3-cylohexanedione 
• 6138-90-5 trans-geranyl bromide 
• 23074-59-1 3-isobutoxycyclohex-2-en-1-one 

Downstream Products

• 100414-93-5 2-(1,1-Dimethoxymethyl)-4-(3,7-dimethylocta-2E,6-dienyl)-1,3,3-trimethyl-1-cyclohexanol 
• 100414-92-4 2-(1,1-Dimethoxymethyl)-3,3-dimethyl-4-(3,7-dimethylocta-2E,6-dienyl)-1-cyclohexanone 
• 100414-91-3 3,3-Dimethyl-4-(3,7-dimethylocta-2E,6-dienyl)-1-trimethylsilyloxy-1-cyclohexene 
• 100414-96-8 3-(3,7-Dimethyl-8-oxo-2E,6E-octadienyl)-2,2,6-trimethyl-1-cyclohexene-1-carboxaldehyde 
• 100414-95-7 3-(3,7-Dimethyl-8-hydroxy-2E,6E-octadienyl)-2,2,6-trimethyl-1-cyclohexene-1-carboxaldehyde 
• 100414-94-6 2,6,6-Trimethyl-5-(3,7-dimethylocta-2E,6-dienyl)-1-cyclohexene-1-carboxaldehyde 
• 100414-90-2 4-(3,7-dimethylocta-2,6-dien-1-yl)-3-methylcyclohex-2-en-1-one 

Relevant articles and documents

Total synthesis of verticillene. A biomimetic approach to the taxane family of alkaloids

Intramolecular reductive coupling of the bis-aldehyde (10) in the presence of Ti(O), followed by 1,4-reducdon of the resulting tetraene (9) using sodium in ammonia, provides a facile synthesis of E,E-verticillene (8), the putative biogenetic precursor of

A Unique Skeletal Rearrangement of a Bicyclo[33.1]nonanetrione to a Tetrahydroquinolin-2(1 H)-one System

The unexpected formation of a 4-hydroxytetrahydroquinolin-2(1 H)-one from a bicyclo[3.3.1]nonanetrione system and an amino alcohol in the presence of TsOH is reported. The mechanism of this transformation was studied by DFT calculations. The reaction provides an entry to the synthesis of highly functionalized 4-hydroxytetrahydroquinolin-2(1 H)-ones.