100414-95-7

Upstream product

• 6138-90-5 trans-geranyl bromide 
• 100414-90-2 4-(3,7-dimethylocta-2,6-dien-1-yl)-3-methylcyclohex-2-en-1-one 
• 100414-91-3 3,3-Dimethyl-4-(3,7-dimethylocta-2E,6-dienyl)-1-trimethylsilyloxy-1-cyclohexene 
• 100414-92-4 2-(1,1-Dimethoxymethyl)-3,3-dimethyl-4-(3,7-dimethylocta-2E,6-dienyl)-1-cyclohexanone 
• 100414-93-5 2-(1,1-Dimethoxymethyl)-4-(3,7-dimethylocta-2E,6-dienyl)-1,3,3-trimethyl-1-cyclohexanol 
• 117360-96-0 3-<(1-methylpropyl)oxy>-2-cyclohexen-1-one 
• 23074-59-1 3-isobutoxycyclohex-2-en-1-one 
• 100414-89-9 6-(3,7-Dimethylocta-2E,6-dienyl)-3-(2-methylpropyloxy)-2-cyclohexen-1-one 
• 100414-94-6 2,6,6-Trimethyl-5-(3,7-dimethylocta-2E,6-dienyl)-1-cyclohexene-1-carboxaldehyde 

Downstream Products

• 100414-96-8 3-(3,7-Dimethyl-8-oxo-2E,6E-octadienyl)-2,2,6-trimethyl-1-cyclohexene-1-carboxaldehyde 

Relevant academic research and scientific papers

Total synthesis of verticillene. A biomimetic approach to the taxane family of alkaloids

Intramolecular reductive coupling of the bis-aldehyde (10) in the presence of Ti(O), followed by 1,4-reducdon of the resulting tetraene (9) using sodium in ammonia, provides a facile synthesis of E,E-verticillene (8), the putative biogenetic precursor of

TOTAL SYNTHESIS OF VERTICILLENE, THE PUTATIVE BIOGENETIC PRECURSOR OF THE TAXANE ALKALOIDS.

Intramolecular reductive coupling of the bis-aldehyde(14) in the presence of Ti(O), followed by 1,4-reduction of the resulting tetraene(16) using sodium in ammonia, provides a facile synthesis of E,E-verticillene(2), the putative biogenetic precursor of t