100419-92-9Relevant articles and documents
Oxidant-induced addition reaction of perfluoroalkyl halides to alkenes and alkynes
Guo, Xiao-Chuan,Chen, Qing-Yun
, p. 63 - 70 (2007/10/03)
Ceric sulfate, cerium (IV) ammonium nitrate, sodium persulfate, ammonium persulfate and potassium permanganate can smoothly induce the addition reaction of perfluoroalkyl halides (1) to electron-rich olefins (2) and alkynes (4) to give monoadducts (3 or 5
STUDIES ON FLUOROALKYLATION AND FLUOROALKOXYLATION. PART 24. MAGNESIUM-INDUCED SINGLE ELECTRON TRANSFER IN REACTIONS OF FLUOROALKYL IODIDES WITH ALKENES AND ALKYNES
Chen, Quing-Yun,Qiu, Zai-Ming,Yang, Zhen-Yu
, p. 149 - 162 (2007/10/02)
Magnesium metal catalyses the radical reactions of perfluoroalkyl iodides with alkenes and alkynes to give the corresponding adducts in high yields under mild conditions.The presence of 1,4-dinitrobenzene (p-DNB) or oxygen does not affect the reaction, bu