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101-01-9

101-01-9

Identification

Synonyms:Guanidine,1,2,3-triphenyl- (6CI,7CI,8CI); 1,2,3-Triphenylguanidine;N,N',N''-Triphenylguanidine; N,N',N''-Triphenylguanidine; NSC 4051;sym-Triphenylguanidine

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Safety information and MSDS view more

  • Signal Word:Warning

  • Hazard Statement:H302 Harmful if swallowed

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price view more

  • Manufacture/Brand
  • Product Description
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  • Purchase
  • Manufacture/Brand:TCI Chemical
  • Product Description:1,2,3-Triphenylguanidine >97.0%(HPLC)(T)
  • Packaging:25g
  • Price:$ 129
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:1,2,3-TRIPHENYLGUANIDINE Aldrich
  • Packaging:1g
  • Price:$ 144
  • Delivery:In stock
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:1,2,3-Triphenylguanidine 95%
  • Packaging:100g
  • Price:$ 710
  • Delivery:In stock
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:1,2,3-Triphenylguanidine 95%
  • Packaging:5g
  • Price:$ 95
  • Delivery:In stock
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:1,2,3-Triphenylguanidine 95%
  • Packaging:10g
  • Price:$ 135
  • Delivery:In stock
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  • Manufacture/Brand:Crysdot
  • Product Description:1,2,3-Triphenylguanidine 95+%
  • Packaging:100g
  • Price:$ 364
  • Delivery:In stock
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:1,2,3-TRIPHENYLGUANIDINE 95.00%
  • Packaging:10G
  • Price:$ 535
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:1,2,3-TRIPHENYLGUANIDINE 95.00%
  • Packaging:5G
  • Price:$ 495
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:1,2,3-TRIPHENYLGUANIDINE 95.00%
  • Packaging:1G
  • Price:$ 419
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:1,2,3-TRIPHENYLGUANIDINE 95.00%
  • Packaging:250MG
  • Price:$ 404.75
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Relevant articles and documentsAll total 14 Articles be found

Novel Desulphurization of Thiourea Derivatives by Alkaline Autoxidation

Kim, Yong Hae,Kim, Hyung Jin,Yon, Gyu Hwan

, p. 1064 - 1065 (1984)

Autoxidation of 1,3-disubstituted thioureas in the presence of oxygen and tertiary butoxide in tertiary butanol afforded the corresponding ureas in good yields together with small amounts of the corresponding guanidines while the same treatment of benz- or naphth-imidazole-2-thiones gave the parent imidazoles and the 2-sulphonic acids.

-

Mc Creath

, p. 383 (1875)

-

-

Tieckelmann,Post

, p. 268,272 (1948)

-

O-Iodoxybenzoic acid mediated oxidative condensation: Synthesis of guanidines using 1,-3-disubstituted thiourea precursors

Dangate, Prasad S.,Akamanchi, Krishnacharya G.

, p. 6765 - 6767 (2013/01/15)

An efficient and mild oxidative condensation procedure using o-iodoxybenzoic acid and triethylamine or ammonia as base has been developed for the synthesis of guanidines starting from easily synthesizable 1,3-disubstituted thioureas and amines or ammonia.

Benzenetellurinic Mixed Anhydrides as Mild Oxidizing Agents

Fukumoto, Takahiro,Matsuki, Toshiaki,Hu, Nan Xing,Aso, Yoshio,Otsubo, Tetsuo,Ogura, Fumio

, p. 2269 - 2272 (2007/10/02)

Three benzenetellurinic mixed anhydrides. i. e. benzenetellurinyl acetate, trifluoroacetate, and trifluoromethanesulfonate, have been found to be mild oxidizing agents for various substrates such as thiol, phosphine, acyloin, α-hydroxy ester, catechol, hydroquinone, thiourea, and thioamide.The reactions towards the last two substrates are highly chemoselective, depending on both the reagent and substrate.

Process route upstream and downstream products

Process route

4,4'-bis-trichloromethylsulfanyl-biphenyl
861533-49-5

4,4'-bis-trichloromethylsulfanyl-biphenyl

aniline
62-53-3

aniline

(1,1'-biphenyl)-4,4'-dithiol
6954-27-4

(1,1'-biphenyl)-4,4'-dithiol

N,N',N''-triphenylguanidine
101-01-9

N,N',N''-triphenylguanidine

Conditions
Conditions Yield
tetrachloromethane
56-23-5

tetrachloromethane

aniline
62-53-3

aniline

N,N',N''-triphenylguanidine
101-01-9

N,N',N''-triphenylguanidine

diphenyl hydrazine
122-66-7

diphenyl hydrazine

phenylcarbonimidic dichloride
622-44-6

phenylcarbonimidic dichloride

Azobenzene
1227476-15-4

Azobenzene

N-phenylphenylene-1,4-diamine
101-54-2

N-phenylphenylene-1,4-diamine

N-phenyl-1,2-benzenediamine
534-85-0

N-phenyl-1,2-benzenediamine

Conditions
Conditions Yield
at 15 ℃; for 24h; Product distribution; Mechanism; Irradiation; also in methanol and 1,4-dioxane;
21.2%
3.1%
31.8%
18.4%
3-phenylimino-3H-benzimidazo<2,1-c><1,2,4>-dithiazole
72885-89-3

3-phenylimino-3H-benzimidazo<2,1-c><1,2,4>-dithiazole

aniline
62-53-3

aniline

2,3-dihydrobenzimidazol-2-thione
583-39-1,2080-59-3

2,3-dihydrobenzimidazol-2-thione

N,N',N''-triphenylguanidine
101-01-9

N,N',N''-triphenylguanidine

Conditions
Conditions Yield
at 90 ℃; for 1h;
87%
91%
5-methyl-1-phenyl-1H-tetrazole
14213-16-2

5-methyl-1-phenyl-1H-tetrazole

N-((methylimino)methylene)aniline
4172-91-2

N-((methylimino)methylene)aniline

2-Methyl-1H-benzimidazole
615-15-6

2-Methyl-1H-benzimidazole

N,N',N''-triphenylguanidine
101-01-9

N,N',N''-triphenylguanidine

1,2-Dimethyl-3-phenylguanidin
10493-81-9

1,2-Dimethyl-3-phenylguanidin

aniline
62-53-3

aniline

1,3-Diphenylcarbodiimide
622-16-2

1,3-Diphenylcarbodiimide

Conditions
Conditions Yield
at 290 ℃; Product distribution; other temperature;
18.4 % Chromat.
11.3 % Chromat.
9.2 % Chromat.
4.6 % Chromat.
4.6 % Chromat.
2.4 % Chromat.
N,N-diphenylthiourea
102-08-9

N,N-diphenylthiourea

N,N',N''-triphenylguanidine
101-01-9

N,N',N''-triphenylguanidine

N<sup>1</sup>,N<sup>2</sup>,N<sup>3</sup>,N<sup>4</sup>,N<sup>5</sup>-Pentaphenylbiguanide
77903-04-9

N1,N2,N3,N4,N5-Pentaphenylbiguanide

1,3-Diphenylcarbodiimide
622-16-2

1,3-Diphenylcarbodiimide

bis(diphenyl)urea
102-07-8

bis(diphenyl)urea

Conditions
Conditions Yield
1,3-bis-trichloromethylsulfanyl-benzene
861601-41-4

1,3-bis-trichloromethylsulfanyl-benzene

aniline
62-53-3

aniline

3-mercaptothiophenol
626-04-0

3-mercaptothiophenol

N,N',N''-triphenylguanidine
101-01-9

N,N',N''-triphenylguanidine

Conditions
Conditions Yield
N-Phenyl-O-p-chlorophenylcarbamate
16323-15-2

N-Phenyl-O-p-chlorophenylcarbamate

5-chlorosalicylanilide
4638-48-6

5-chlorosalicylanilide

N,N',N''-triphenylguanidine
101-01-9

N,N',N''-triphenylguanidine

Conditions
Conditions Yield
at 200 ℃;
orthocarbonic acid tetraethyl ester
78-09-1

orthocarbonic acid tetraethyl ester

aniline
62-53-3

aniline

N,N-diphenylurea
603-54-3

N,N-diphenylurea

N,N',N''-triphenylguanidine
101-01-9

N,N',N''-triphenylguanidine

Conditions
Conditions Yield
at 250 ℃;
orthocarbonic acid tetraethyl ester
78-09-1

orthocarbonic acid tetraethyl ester

aniline
62-53-3

aniline

N,N-diphenylurea
603-54-3

N,N-diphenylurea

Diethyl(phenylimido)carbonat
6263-08-7

Diethyl(phenylimido)carbonat

N,N',N''-triphenylguanidine
101-01-9

N,N',N''-triphenylguanidine

Conditions
Conditions Yield
at 250 ℃;
pyridine
110-86-1

pyridine

1,3-diphenyl-selenourea
16519-43-0

1,3-diphenyl-selenourea

N,N-diphenylurea
603-54-3

N,N-diphenylurea

N,N',N''-triphenylguanidine
101-01-9

N,N',N''-triphenylguanidine

aniline
62-53-3

aniline

Conditions
Conditions Yield

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