10298-87-0Relevant articles and documents
A new route to boron nitride
Economy,Anderson
, p. 989 - 992 (1966)
A new synthesis is described for preparation of boron nitride from the reaction of an alkyl polyborate-ammonia complex (RO)3B25O36·(NH3)8 with ammonia in the temperature range of 400-800°. The ammonia complex is obtained via a novel disproportionation of a trialkoxyboroxine to the corresponding trialkoxyborane and the ammonia complex. Boron nitride obtained under these conditions possesses a turbostratic structure.
PROCESS FOR SYNTHESIS OF DIALKOXYORGANOBORANES
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Page/Page column 9, (2008/06/13)
The invention relates to a process for the synthesis of dialkoxyorganoboranes, in particular to a process for the synthesis of dialkoxyorganoboranes by an ester exchange reaction. Moreover, the invention relates to a process for the synthesis of organo-oxazaborolidine catalysts (organo-CBS) and of trialkylboroxins. Furthermore, the invention relates to methods of using dialkoxyorganoboranes for the preparation of organo-CBS catalysts and in Suzuki-type coupling reactions.