104870-79-3Relevant articles and documents
Stereoselective cathodic synthesis of 8-substituted (1R,3R,4S)-menthylamines
Edinger, Carolin,Kulisch, J?rn,Waldvogel, Siegfried R.
, p. 294 - 301 (2015)
The electrochemical generation of menthylamines from the corresponding menthone oximes equipped with an additional substituent in position 8 is described. Due to 1,3-diaxial interactions a pronounced diastereoselectivity for the menthylamines is found.
Chiral auxiliaries with a switching center: New tools in asymmetric synthesis. Application to the synthesis of enantiomerically pure (R)- and (S)-α-amino acids
Meyer,Poirier,Duhamel,Duhamel
, p. 8094 - 8095 (2007/10/03)
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Large-Scale Preparation of Pure (+)-(1S,2R,5S)-5-Methyl-2-(1-methyl-1-phenylethyl)cyclohexanol
Buschmann, Helmut,Scharf, Hans-Dieter
, p. 827 - 830 (2007/10/02)
A procedure is described for the preparation of (S)-(-)pulegone, (-)-1, starting from (S)-(-)citronellol, (-)-6, in a preparative scale.Compound (-)-1 can easily be converted into (+)-(1S,2R,5S)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexanol: (+)-2 by a procedure described in literature, which was simplified essentially.Now (+)-2 is accessible in larger amounts and thus is available as an efficient chiral auxiliary in stoichiometric asymmetric syntheses.