10575-55-0Relevant articles and documents
Solvent- A nd anion-dependent rearrangement of fluorinated carbene ligands provides access to fluorinated alkenes
Hall, Lewis M.,Milner, Lucy M.,Hart, Sam J.,Whitwood, Adrian C.,Lynam, Jason M.,Slattery, John M.
, p. 17655 - 17659 (2019)
The construction of fluorocarbene ligands within the coordination sphere of transition metal complexes using sequential nucleophilic and electrophilic addition to a vinylidene complex is described. Reaction of [Ru(η5-C5H5)(dppe)(CCPhF)][N(SO2Ph)2] with [NMe4]F results in nucleophilic attack of fluoride at the metal-bound carbon of the vinylidene ligand to give alkenyl complex [Ru(η5-C5H5)(dppe)(-CFCFPh)]. Subsequent eletrophilic fluorination with N-fluorobenzenesulfonimide (NFSI) results in the formation of the fluorinated carbene complex [Ru(η5-C5H5)(dppe)(CF-CHFPh)][N(SO2Ph)2]. The fluorocarbene complexes undergo rearrangement to liberate free fluorinated alkenes, a process governed by the choice of solvent and anion, representing a new metal-mediated route to fluorinated alkenes from alkynes.
La chlorodesilylation des fluorovinylsilanes. Un cas de retention de configuration
Tellier, Frederique,Sauvetre, Raymond,Normant, Jean-F.
, p. 23 - 30 (2007/10/02)
An overall retention of configuration is observed during the chlorodesilylation of (Z)-1-silyl-1,2-difluoroalkanes, carried out in the presence of fluoride ion and in a polar solvent.