89263-98-9Relevant articles and documents
A Novel Stereospecific Route to (E)- And (Z)-(2-Substituted-1,2-difluoroethenyl)stannanes
Xue, Ling,Lu, Long,Pedersen, Scot D.,Liu, Qibo,Narske, Robert M.,Burton, Donald J.
, p. 1064 - 1071 (1997)
In the presence of 1.2-1.5 equiv of potassium fluoride, a variety of (E)- and (Z)-(2-substituted-1,2-difluoroethenyl)silanes reacted with tributyltin chloride in DMF at room temperature to 80 °C to afford the corresponding stannanes in good yields with overall retention of configuration. These stannanes are useful intermediates for the introduction of the (E)- and (Z)-1,2-difluoroethylene unit into organic molecules. Under similar reaction conditions, only catalytic potassium fluoride (5-10%) was needed for these conversions when tributyltin chloride was replaced by tributyltin oxide. The mechanism and scope of this transformation is discussed.
SYNTHESE DE DIFLUOROALCENES-trans
Martin, Sophie,Sauvetre, Raymond,Normant, Jean-F.
, p. 155 - 162 (2007/10/02)
Several trans-difluoro olefins have been prepared from chlorotrifluoroethylene via difluorovinylsilicon intermediates.