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105786-39-8

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105786-39-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 105786-39-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,5,7,8 and 6 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 105786-39:
(8*1)+(7*0)+(6*5)+(5*7)+(4*8)+(3*6)+(2*3)+(1*9)=138
138 % 10 = 8
So 105786-39-8 is a valid CAS Registry Number.
InChI:InChI=1/C8H14N2O/c9-7-5-2-1-4(3-5)6(7)8(10)11/h4-7H,1-3,9H2,(H2,10,11)/t4-,5+,6+,7-/m0/s1

105786-39-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name DIEXO-3-AMINO-BICYCLO(2.2.1)HEPTANE-2-CARBOXYLIC ACID AMIDE

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:105786-39-8 SDS

105786-39-8Relevant articles and documents

Intermolecular aminocarbonylation of alkenes using concerted cycloadditions of iminoisocyanates

Bongers, Amanda,Clavette, Christian,Gan, Wei,Gorelsky, Serge I.,Betit, Lyanne,Lavergne, Kaitlyn,Markiewicz, Thomas,Moon, Patrick J.,Neves, Nicolas Das,Obhi, Nimrat K.,Toderian, Amy B.,Beauchemin, Andrei M.

, p. 1175 - 1194 (2017/11/14)

The aminocarbonylation of alkenes is a powerful method for accessing the β-amino carbonyl motif that remains underdeveloped. Herein, the development of intermolecular aminocarbonylation reactivity of iminoisocyanates with alkenes is presented. This includes the discovery of a fluorenone-derived reagent, which was effective for many alkene classes and facilitated derivatization. Electron-rich substrates were most reactive, and this indicated that the LUMO of the iminoisocyanate is reacting with the HOMO of the alkene. Computational and experimental results support a concerted asynchronous [3 + 2] cycloaddition involving an iminoisocyanate, which was observed for the first time by FTIR under the reaction conditions. The products of this reaction are complex azomethine imines, which are precursors to valuable β-amino carbonyl compounds such as β-amino amides and esters, pyrazolones, and bicyclic pyrazolidinones. A kinetic resolution of the azomethine imines by enantioselective reduction (s = 13.43) allows access to enantioenriched products. Overall, this work provides a new tool to convert alkenes into β-amino carbonyl compounds.

A tunable route for the synthesis of azomethine imines and β-aminocarbonyl compounds from alkenes

Clavette, Christian,Gan, Wei,Bongers, Amanda,Markiewicz, Thomas,Toderian, Amy B.,Gorelsky, Serge I.,Beauchemin, Andre M.

, p. 16111 - 16114,4 (2020/09/09)

Cyclic azomethine imines possessing a β-aminocarbonyl motif are accessed from simple alkene and hydrazone starting materials. A thermal, concerted alkene aminocarbonylation pathway involving an imino-isocyanate intermediate is proposed and supported by DF

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