105906-36-3

Basic information

• Product Name: MONOBROMODIBENZO-PARA-DIOXIN
• Synonyms: 2-BROMODIBENZO-PARA-DIOXIN;2-bromodibenzo-p-dioxin;2-Bromo-Dibenzo[b,e][1,4]dioxin;2-Bromooxanthrene
• CAS NO: 105906-36-3
• Molecular Formula: C₁₂H₇BrO₂
• Molecular Weight: 263.09
• Mol File: 105906-36-3.mol

Chemical Properties

• Boiling Point: 329.2°Cat760mmHg
• Flash Point: 152.3°C
• Appearance: /
• Density: 1.6g/cm³
• Vapor Pressure: 0.000344mmHg at 25°C
• Refractive Index: 1.651
• CAS DataBase Reference: MONOBROMODIBENZO-PARA-DIOXIN(CAS DataBase Reference)
• NIST Chemistry Reference: MONOBROMODIBENZO-PARA-DIOXIN(105906-36-3)
• EPA Substance Registry System: MONOBROMODIBENZO-PARA-DIOXIN(105906-36-3)

Safety Data

• Hazardous Substances Data: 105906-36-3(Hazardous Substances Data)

Usage

Uses

Given the highly toxic and pollutant nature of MONOBROMODIBENZO-PARA-DIOXIN, it does not have typical applications like other chemicals. However, it is important to note its formation as a byproduct in certain industrial processes and its presence in industrial waste and emissions. The primary focus regarding MONOBROMODIBENZO-PARA-DIOXIN is on its regulation and reduction to mitigate its harmful effects on human health and the environment.
Used in Environmental Regulation and Pollution Control:
MONOBROMODIBENZO-PARA-DIOXIN is a concern for environmental agencies and industries involved in the production of brominated flame retardants. Efforts are made to regulate and reduce its release into the environment to minimize its impact on ecosystems and human health.
Used in Industrial Waste Management:
In industries that produce or use brominated flame retardants, MONOBROMODIBENZO-PARA-DIOXIN is managed as part of waste treatment processes. It is treated and disposed of in a manner that prevents its release into the environment, thereby reducing its potential to cause harm.
Used in Research and Toxicology Studies:
MONOBROMODIBENZO-PARA-DIOXIN is also used as a subject of research in toxicology and environmental science. Studies on MONOBROMODIBENZO-PARA-DIOXIN help in understanding its toxic effects, environmental behavior, and potential risks associated with exposure. This knowledge aids in developing strategies for its control and management.

InChI:InChI=1/C12H7BrO2/c13-8-5-6-11-12(7-8)15-10-4-2-1-3-9(10)14-11/h1-7H

Upstream product

• 348-61-8 1-bromo-3,4-difluorobenzene 
• 120-80-9 benzene-1,2-diol 
• 139458-06-3 2-trimethylsilyldibenzo<1,4>dioxin 
• 95-50-1 1,2-dichloro-benzene 
• 262-12-4 dioxin 

Downstream Products

• 868380-13-6 dibenzo[b,e][1,4]dioxin-2-ylboronic acid 

Relevant articles and documents

Synthesis of mixed halogenated dibenzodioxins (X = Br, Cl)

The conversion of dibenzodioxin with CuCl2x2H2O and CuBr2 results in polyhalogenated dibenzodioxins. Besides the chlorinated compounds, bromination stages 1 to 5 are obtained at chlorination levels of 0 to 7 for monobromo-, 0 to 7 for dibromo-, 0 to 4 for tribromo-, 0 to 3 for tetrabromo-, and 0 to 1 for pentabromodibenzodioxin. The 2,3,7,8 position is halogenated preferentially.

2-bromo-dibenzo[1,4]dioxane compound as well as preparation method and application thereof

The invention discloses a 2-bromo-dibenzo[1,4]dioxane compound, a preparation method and application, and relates to the technical field of organic synthesis. The preparation method comprises the following steps that 3, 4-difluorobromobenzene and catechol serve as raw materials, and under the alkaline condition, 2-bromo-dibenzo[1,4]dioxane is prepared through ring closing. The method provided by the invention adopts easily available raw materials, is efficient and safe in preparation process, is simple to operate, and is suitable for industrial production.

ORDER OF THE REPLACEMENT OF HYDROGEN BY HALOGEN IN THE HALOGENATION OF DIBENZO-p-DIOXIN AND ITS NITRO AND AMINO DERIVATIVES

The order of the replacement of hydrogen by halogen in the bromination and chlorination of dibenzo-p-dioxin and its nitro and amino derivatives was examined with the purpose of determining the possibilities of the formation of highly toxic isomers of halogenated dibenzo-p-dioxins from precursors with a tricyclic structure of dibenzo-p-dioxin.A number of halogenated dibenzo-p-dioxins were synthesized, which illustrates the order of the replacement, and their physicochemical and spectral characteristics are given.

Syntheses of dibenzodioxin derivatives via iron complexes, and further functionalizations via directed metallation

Double nucleophilic aromatic substitution reactions between (cyclopentadienyl)(η6-1,2-dichlorobenzene)iron(1 +) salts and substituted 1,2-benzenediols have been carried out under mild conditions to prepare 6-dibenzodioxin>iron(1 +) complexes functionalized in the 1- or 2-position with an alkyl, aldehyde, carboxylic acid, methoxycarbonyl, carboxamide, or hydroxy group. 3-Methyl- and 4-methyl-(η6-1,2-dichlorobenzene)iron complexes were treated with substituted 1,2-benzenediols to effect functionalization of both aromatic rings of the heterocycle.The dibenzodioxin ligands were liberated routinely by irradiation with ultraviolet light.Directed deprotonation of the free functionalized dibenzodioxins with an alkyllithium reagent followed by quenching with a variety of electrophiles yielded further derivatives, including two new isoindolone systems.